Journal of Organometallic Chemistry p. 343 - 352 (1981)
Update date:2022-08-03
Topics:
Hoberg, Heinz
Burkhart, Georg
Krueger, C.
Tsay, Y. -H
The complex (Ph3P)Ni(PhNCNPh) (II) is formed from (Ph3P)2Ni(PhNCNPh) (I) in toluene at 60 deg C.II can also be prepared directly from (COD)2Ni, Ph3P and PhNCNPh (45percent yield). (COD)2Ni reacts with diarylcarbodiimides in THF to give (ArNCNAr)3Ni(THF) (VIII).The structure of VIIIa (Ar = phenyl) has been determined by X-ray crystallography.The molecule is shown to contain a <3.3.0>nickela bicyclic group in which the carbodiimide molecules are linked to form a 2,5,8-h3-carbene ligand.Some properties and reactions of II and VIII are described.
View MoreJiangxi Dongxu Chemical Science & Technology Co.,Ltd
Contact:+86-791-86899381
Address:Nanchang, Jiangxi, China
Sichuan Highlight Fine Chemicals Co., Ltd.
Contact:+86-28-8525 1605
Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
Contact:+86 21 5017 5386
Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
Lishui Nanming Chemical Co., Ltd
Contact:+86-0578-2134101,2697830
Address:No.19 Tongji Road Shuige Industrial zone
Zhuzhou Farshine Chemical Industry Co., Ltd
Contact:0086-731-28482786
Address:No. 1,Shui Xian Road, He Tang Dictrict,Hunan-412000,China
Doi:10.1021/jo00348a041
(1982)Doi:10.1021/jo00132a008
(1982)Doi:10.1039/c39900001664
(1990)Doi:10.1016/S0040-4039(01)82972-5
(1981)Doi:10.1021/acs.orglett.8b01840
(2018)Doi:10.1016/S0040-4039(01)83025-2
(1981)