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2
4
CF SO H were charged into a 50 mL stainless steel autoclave.
3
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The autoclave was sealed and flushed with 2 MPa of CO three
2
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desired reaction temperature while stirring. CO was then intro-
2
2
duced into the autoclave to the desired pressure using a high-
pressure pump. The autoclave was cooled to room temperature
after a certain reaction time, and the pressure was gradually
released. Water (5mL) was added after the reaction mixture was
cooled to room temperature, and the mixture was extracted with
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3
ꢁ 5 mL of hexane. The combined organic extracts were washed
[
[
[
with 2 ꢁ 5 mL of water and dried over sodium sulfate. The
products were then analysed by GC using an internal standard.
The yields of the products were based on the charged phenol. The
product and by-products were also identified by GC-MS.
The conversion of phenol, yield, and selectivity towards DPC
were analysed using a GC2020 gas chromatograph with HP-5
capillary column (30 m ꢁ 0.32 mm ꢁ 0.25 mm, 5 % phenyl
methyl-siloxane) and FID detector. GC-MS analyses were
performed using an Agilent 7890A/5975C GC equipped with
a HP-5 capillary column and electron ionization source. The
detection was performed in the scan mode from m/z 20 to 400.
2
2
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Helium (1.0 mL min ) was used as the carrier gas. The ioniza-
tion voltage and source temperature was 70 eV and 2308C,
respectively.
Acknowledgements
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This work was supported by the Hubei Provincial Natural Science Foun-
dation of China (No. 2011CDC114) and the Wuhan Science and Technology
Bureau Key Scientific and Technological project (No. 201220822275).
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