100
I. Hatanaka et al. / Journal of Organometallic Chemistry 674 (2003) 96Á100
/
Fig. 10. Possible mechanism.
4. Experimental
Acknowledgements
(TBA)SiW6Mo6O40 and (TBA)SiMo11O40 were
synthesized according to the reported method [17]. All
other reagents were obtained from commercial sources
and used as received. Molecular sieve (M.S.) was
activated at 450 8C in air for 10 h before use. All the
reactions are run in an autoclave by flow system except
the one done for Pd TON using tributylamine and
TBAB under a normal pressure.
T.Y., K.K. and T.K. thank RITE (Research Institute
of Innovative Technology for the Earth) for the support
of this research. HPAs were generously gifted by
Nippon Inorganic Color and Chemical Co. Ltd.
References
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4H2O (0.078 g, 0.32
(0.036 g, 0.16 mmol), Mn(OAc)2×
/
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