Anthracene, 2,3,6,7-tetramethyl-9-phenyl-

Base Information

• Chemical Name: Anthracene, 2,3,6,7-tetramethyl-9-phenyl-
• CAS No.: 59146-18-8
• Molecular Formula: C24H22
• Molecular Weight: 310.439
• Mol file: 59146-18-8.mol

Synonyms:

Chemical Property of Anthracene, 2,3,6,7-tetramethyl-9-phenyl-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Anthracene, 2,3,6,7-tetramethyl-9-phenyl-

There total 3 articles about Anthracene, 2,3,6,7-tetramethyl-9-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

bromobenzene (108-86-1,52753-63-6) + 2,3,6,7-tetramethylanthrone (676363-02-3) → 9-phenyl-2,3,6,7-tetramethylanthracene (59146-18-8)

Guidance literature:

bromobenzene; With magnesium; In diethyl ether;

2,3,6,7-tetramethylanthrone; In diethyl ether; for 4h; Heating;

DOI:10.1021/jo035517i

Reference yield:

2,3,6,7-tetramethylanthracene-9,10-dione (15247-68-4) → 9-phenyl-2,3,6,7-tetramethylanthracene (59146-18-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 82 percent / Sn; HCl

2.1: Mg / diethyl ether

2.2: 82 percent / diethyl ether / 4 h / Heating

With hydrogenchloride; tin; magnesium; In diethyl ether; 1.1: Clemensen reduction;

DOI:10.1021/jo035517i

Reference yield:

2,3,6,7-tetramethyl-1,4,4a,5,8,8a,9a,10a-octahydroanthracene-9,10-dione (15254-26-9) → 9-phenyl-2,3,6,7-tetramethylanthracene (59146-18-8)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 98 percent / KOH; O₂ / ethanol

2.1: 82 percent / Sn; HCl

3.1: Mg / diethyl ether

3.2: 82 percent / diethyl ether / 4 h / Heating

With hydrogenchloride; potassium hydroxide; tin; oxygen; magnesium; In diethyl ether; ethanol; 2.1: Clemensen reduction;

DOI:10.1021/jo035517i

upstream raw materials:

bromobenzene

2,3,6,7-tetramethylanthrone

2,3,6,7-tetramethylanthracene-9,10-dione

2,3,6,7-tetramethyl-1,4,4a,5,8,8a,9a,10a-octahydroanthracene-9,10-dione

Downstream raw materials:

10-(3-hydroxy-3-methyl-1-butynyl)-2,3,6,7-tetramethyl-9-phenylanthracene

10-bromo-2,3,6,7-tetramethyl-9-phenylanthracene

Refernces