3-Methoxycarbonyl-2,2'-dinaphthylamin

Base Information

• Chemical Name: 3-Methoxycarbonyl-2,2'-dinaphthylamin
• CAS No.: 97015-51-5
• Molecular Formula: C₂₂H₁₇NO₂
• Molecular Weight: 327.382
• Mol file: 97015-51-5.mol

Synonyms:3-Methoxycarbonyl-2,2'-dinaphthylamin

Chemical Property of 3-Methoxycarbonyl-2,2'-dinaphthylamin

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 3-Methoxycarbonyl-2,2'-dinaphthylamin

There total 1 articles about 3-Methoxycarbonyl-2,2'-dinaphthylamin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-bromo-2-naphthalenecarboxaldehyde (89005-11-8) → 3-Methoxycarbonyl-2,2'-dinaphthylamin (97015-51-5)

Guidance literature:

Multi-step reaction with 3 steps

1: sodium dihydrogenphosphate; sodium chlorite; water / tert-butyl alcohol / 24 h / 20 °C

2: thionyl chloride / 12 h / Reflux

3: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate / toluene / 16 h / 120 °C / Inert atmosphere

With sodium chlorite; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; sodium dihydrogenphosphate; thionyl chloride; water; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate; In toluene; tert-butyl alcohol; 3: |Buchwald-Hartwig Coupling;

DOI:10.1002/ejoc.202000871

upstream raw materials:

3-bromo-2-naphthalenecarboxaldehyde

Refernces