1,1,1-Triphenyl-N-(triphenylphosphoranylidene)phosphoraniminium 2,2,2-trifluoroacetate

Base Information

• Chemical Name: 1,1,1-Triphenyl-N-(triphenylphosphoranylidene)phosphoraniminium 2,2,2-trifluoroacetate
• CAS No.: 116405-43-7
• Molecular Formula: C₂F₃O₂*C₃₆H₃₀NP₂
• Molecular Weight: 651.604
• DSSTox Substance ID: DTXSID10600070
• Mol file: 116405-43-7.mol

Synonyms:116405-43-7;1,1,1-Triphenyl-N-(triphenylphosphoranylidene)phosphoraniminium 2,2,2-trifluoroacetate;Bis(triphenylphosphine)iminium trifluoroacetate;2,2,2-trifluoroacetate;triphenyl-[(triphenyl-lambda5-phosphanylidene)amino]phosphanium;BIS(TRIPHENYL-??-PHOSPHANYLIDENE)AZANIUM TRIFLUOROACETATE;Phosphorus(1+), triphenyl(P,P,P-triphenylphosphine imidato-kappaN)-, (T-4)-, 2,2,2-trifluoroacetate (1:1);SCHEMBL9580020;DTXSID10600070;BCP21898;AKOS016008552;CS-W009584;AS-74760;A893575;J-519893;Bis(triphenylphosphoranylidene)ammonium trifluoroacetate;BIS-(TRIPHENYLPHOSPHORANYLIDENE) AMMONIUM TFA (PPN TFA);triphenyl[(triphenyl-??-phosphanylidene)amino]phosphanium trifluoroacetate;1,1,1-Triphenyl-N-(triphenylphosphoranylidene)-phosphoraniminium 2,2,2-trifluoroacetate;1,1,1-Triphenyl-N-(triphenylphosphoranylidene)phosphoraniminium2,2,2-trifluoroacetate;Triphenyl-N-(triphenyl-lambda~5~-phosphanylidene)-lambda~5~-phosphaniminium trifluoroacetate

Chemical Property of 1,1,1-Triphenyl-N-(triphenylphosphoranylidene)phosphoraniminium 2,2,2-trifluoroacetate

Chemical Property:

• PSA: 59.75000
• LogP: 5.70760
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 7
• Exact Mass: 651.17038768
• Heavy Atom Count: 46
• Complexity: 685

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bis(triphenylphosphine)iminiumTrifluoroacetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(=N[P+](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6.C(=O)(C(F)(F)F)[O-]
• Uses: suzuki reaction Bis(triphenylphosphine)iminium trifluoroacetate is used as pharmaceutical intermediates and chemical intermediate.

Technology Process of 1,1,1-Triphenyl-N-(triphenylphosphoranylidene)phosphoraniminium 2,2,2-trifluoroacetate

There total 3 articles about 1,1,1-Triphenyl-N-(triphenylphosphoranylidene)phosphoraniminium 2,2,2-trifluoroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

→ bis(triphenylphosphonium)nitrogen trifluoroacetate (116405-43-7)

Guidance literature:

Reference yield:

bis(triphenylphosphine)iminium chloride (21050-13-5) + trifluoroacetic acid (76-05-1) → bis(triphenylphosphonium)nitrogen trifluoroacetate (116405-43-7)

Guidance literature:

With sodium hydroxide; In water; for 0.166667h; Heating;

DOI:10.1021/jacs.6b03113

Reference yield:

sodium 2,2,2-trifluoroacetate (2923-18-4) + bis(triphenylphosphine)iminium chloride (21050-13-5) → bis(triphenylphosphonium)nitrogen trifluoroacetate (116405-43-7)

Guidance literature:

In water; for 0.333333h;

DOI:10.1002/anie.201801380

upstream raw materials:

bis(triphenylphosphine)iminium chloride

trifluoroacetic acid

sodium 2,2,2-trifluoroacetate

Refernces

• 1、 Morris, Lilliana S.,Childers, M. Ian,Coates, Geoffrey W.. "Bimetallic Chromium Catalysts with Chain Transfer Agents: A Route to Isotactic Poly(propylene oxide)s with Narrow Dispersities". . p. 5731 - 5734. Retrieved 2018.