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| CAS No.: | 93-89-0 |
|---|---|
| Name: | Ethyl benzoate |
| Article Data: | 1022 |
| Molecular Structure: | |
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| Formula: | C9H10O2 |
| Molecular Weight: | 150.177 |
| Synonyms: | Benzoyl ethyl ether;Ethyl benzenecarboxylate;AI3-01352;Benzoic acid, ethyl ester;Benzoic ether;Ethyl benzoate (natural);Ethylester kyseliny benzoove;Ethylester kyseliny benzoove [Czech];FEMA No. 2422;NSC 8884; |
| EINECS: | 202-284-3 |
| Density: | 1.044 g/cm3 |
| Melting Point: | -34 °C |
| Boiling Point: | 211.7 °C at 760 mmHg |
| Flash Point: | 88.9 °C |
| Solubility: | insoluble in water |
| Appearance: | clear, colorless to pale yellow liquid |
| Hazard Symbols: | N |
| Risk Codes: | 51/53 |
| Safety: | 24/25 |
| PSA: | 26.30000 |
| LogP: | 1.86330 |
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Consensus Reports
Reported in EPA TSCA Inventory.
Specification
1. Introduction of Ethyl benzoate
Ethyl benzoate is a colorless to pale yellow colored chemical compound with a pleasant wintergreen mint flavor used as a food flavoring agent. It is alse called Benzoic acid, ethyl ester; Benzoic ether; Benzoyl ethyl ether; Ethyl benzenecarboxylate ; Ethyl benzoate (natural); Ethylester kyseliny benzoove; Ethylester kyseliny benzoove [Czech] and so on.
2. Properties of Ethyl benzoate
Melting point: -34 °C
Polar Surface Area: 26.3 Å2
Index of Refraction: 1.504
Molar Refractivity: 42.65 cm3
Molar Volume: 143.8 cm3
Surface Tension: 35.8 dyne/cm
Density: 1.044 g/cm3
Flash Point: 88.9 °C
Enthalpy of Vaporization: 44.8 kJ/mol
Boiling Point: 211.7 °C at 760 mmHg
Vapour Pressure: 0.18 mmHg at 25°C
3. Toxicity of Ethyl benzoate
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| cat | LDLo | skin | 10gm/kg (10000mg/kg) | BEHAVIORAL: TREMOR BEHAVIORAL: MUSCLE WEAKNESS GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS | Journal of Pharmacology and Experimental Therapeutics. Vol. 84, Pg. 358, 1945. |
| rabbit | LD50 | oral | 2630mg/kg (2630mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: MUSCLE WEAKNESS SKIN AND APPENDAGES (SKIN): HAIR: OTHER | Journal of Pharmacology and Experimental Therapeutics. Vol. 84, Pg. 358, 1945. |
| rat | LD50 | oral | 2100mg/kg (2100mg/kg) | BEHAVIORAL: MUSCLE WEAKNESS LUNGS, THORAX, OR RESPIRATION: DYSPNEA SKIN AND APPENDAGES (SKIN): HAIR: OTHER | Journal of Pharmacology and Experimental Therapeutics. Vol. 84, Pg. 358, 1945. |
4. Safety Information of Ethyl benzoate
Safety Statements: 24/25
S24/25: Avoid contact with skin and eyes.
WGK Germany: 1
RTECS: DH0200000
HS Code: 29163100
Moderately toxic by ingestion. Mildly toxic by skin contact. A skin and eye irritant. Combustible liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
5. Preparation of Ethyl benzoate
Ethyl benzoate is synthetically produced by the condensation of benzoic acid and ethanol with the help of sulphuric acid. What's more, ethyl benzoate is naturally found in many ingredients, especially in fruits such as banana, apple, cranberry, cherry, peach, kiwi, grape, star fruit, black currant, raspberry, etc.
6. Use of Ethyl benzoate
Because of its pleasant mixed fruity and woody odor, Ethyl benzoate is used as a perfume scent under the name essence de niobe.
7. Other details of Ethyl benzoate
Ethyl benzoate is a volatile compound and tends to cause irritation of skin, eyes and respiratory tract, if inhaled. Moreover, it tends to react adversely with acidic and alkaline substances and also with oxidizing agents. Considering all these, this compound needs to be stored in airtight and non-corroding containers away from direct sunlight. It needs to be stored in a cool, dry and well ventilated place.
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