109787-95-3Relevant articles and documents
Synthesis of 5-Vinyl-2-isoxazolines by Palladium-Catalyzed Intramolecular O-Allylation of Ketoximes
Fernandes, Rodney A.,Gangani, Ashvin J.,Panja, Arpita
supporting information, p. 6227 - 6231 (2021/08/18)
An efficient method for the synthesis of 5-vinyl-2-isoxazolines by Pd-catalyzed intramolecular O-allylation of ketoximes has been developed. The reaction involves Pd(0)-catalyzed π-allyl formation via leaving group ionization or Pd(II)-catalyzed allylic C-H activation followed by intramolecular nucleophilic oxime oxygen attack. This methodology has been elaborated to various value-added products by epoxidation, Wacker oxidation, cross-metathesis, hydroboration-oxidation, dihydroxylation, and catalytic hydrogenation.
A facile synthesis of α-fluoro ketones catalyzed by [Cp*IrCl2]2
Ahlsten, Nanna,Bartoszewicz, Agnieszka,Agrawal, Santosh,Martin-Matute, Belen
supporting information; experimental part, p. 2600 - 2608 (2011/10/02)
Allylic alcohols are isomerized into enolates (enols) by [Cp*IrCl2]2. The enolates react with Selectfluor present in the reaction media. This method produces α-fluoro ketones as single constitutional isomers in high yields. Georg Thieme Verlag Stuttgart. New York.
Stereoselective Intramolecular Iodoetherification of 4-pentene-1,3-diols: Synthesis of cis-2-(Iodomethyl)-3-hydroxytetrahydrofurans
Tamaru, Yoshinao,Hojo, Makoto,Kawamura, Shin-ichi,Sawada, Shuji,Yoshida, Zen-ichi
, p. 4062 - 4072 (2007/10/02)
Intramolecular iodoetherification of 4-pentene-1,3-diol and its monosubstituted derivatives, irrespective of the substitution pattern, provides cis-2-(iodomethyl)-3-hydroxytetrahydrofurans in high yields.The cis selectivity generally exceeds 95percent .So
