13313-19-4Relevant articles and documents
Studies on the Oxidation of the Azomethine Compounds with 3-Chloroperbenzoic Acid
Mlochowski, J.,Abdel-Latif, F. F.,Kubicz, E.,Said, S. B.
, p. 711 - 722 (2007/10/02)
Oxidation of the azomethine compounds such as Schiff bases and azines having several nucleophilic centers with 3-chloroperbenzoic acid (MCPBA) being an electrophilic oxidant was investigated.From azines 4, bisaldimines 5, 6, and pyridine derived monoaldimines 7, 8, having various substituents on the imine carbon and nitrogen atoms, the products such as nitrones 9, 15, bisoxaziridines 11, 12; acyldiimine 10 and amide 14 were obtained in high yields.The influence of the structure of substrate on the reaction result is discussed.Key words: aldimines, azines, nitrones, oxaziridines