43020-10-6

Basic information

• Product Name: Ethanone, 1-(2-Methyl-5-phenyl-3-furanyl)-
• Synonyms: Ethanone, 1-(2-Methyl-5-phenyl-3-furanyl)-
• CAS NO: 43020-10-6
• Molecular Formula: C₁₃H₁₂O₂
• Molecular Weight: 200.23318
• Mol File: 43020-10-6.mol
• Article Data: 14

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-(2-Methyl-5-phenyl-3-furanyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(2-Methyl-5-phenyl-3-furanyl)-(43020-10-6)
• EPA Substance Registry System: Ethanone, 1-(2-Methyl-5-phenyl-3-furanyl)-(43020-10-6)

Safety Data

• Hazardous Substances Data: 43020-10-6(Hazardous Substances Data)

Usage

General Description

Ethanone, 1-(2-methyl-5-phenyl-3-furanyl)- is a chemical compound with a molecular formula C14H12O2. It is also known as 2-Methyl-5-phenyl-3-furylmethylketone and is commonly used in research and laboratory settings. Ethanone, 1-(2-methyl-5-phenyl-3-furanyl)- is a furan derivative and features a furan ring with a phenyl and methyl group attached. Ethanone, 1-(2-methyl-5-phenyl-3-furanyl)- has potential applications in various fields, including pharmaceuticals and organic synthesis, due to its unique structural properties and reactivity. However, further studies are needed to fully understand its potential uses and properties in different industries.

Upstream product

• 133216-64-5 4-acetyl-3-methyl-6,6-diphenyl-1,2-dioxan-3-ol 
• 123-54-6 acetylacetone 
• 1074-12-0 phenylglyoxal hydrate 
• 29397-21-5 Diacetyldiazomethan 
• 536-74-3 phenylacetylene 
• 52313-43-6 3-acetyl-1-phenyl-pentane-1,4-dione 
• 93-91-4 1-phenylbutan-1,3-dione 
• 122-78-1 phenylacetaldehyde 
• 33440-88-9 silver phenylacetylide 
• 932-87-6 1-Bromo-2-phenylacetylene 
• 2170-06-1 1-Phenyl-2-(trimethylsilyl)acetylene 
• 98-86-2 acetophenone 
• 57957-24-1 N-(1-phenylvinyl)acetamide 
• 4747-15-3 1-(2-methoxyvinyl)benzene 

Downstream Products

• 96460-72-9 (2-methyl-5-phenyl-[3]furyl)-glyoxylonitrile 
• 108124-17-0 2-methyl-5-phenyl-furan-3-carboxylic acid 
• 90043-48-4 (3R,3aR,6aS)-4-Acetyl-5-methyl-2-oxo-6a-phenyl-2,3,3a,6a-tetrahydro-furo[2,3-b]furan-3-carboxylic acid methyl ester 
• 90043-63-3 2,2-diacetyl-3-benzoyloxirane 
• 89201-18-3 3-acetyl-1-phenyl-2-pentene-1,4-dione 
• 90043-52-0 5-Acetyl-4-methyl-1-phenyl-2,3,7-trioxabicyclo<2.2.1>hept-5-ene 
• 109218-94-2 2-(2-methyl-5-phenyl-[3]furyl)-glyoxal-1-oxime 

Relevant articles and documents

Photocatalytic synthesis of tetra-substituted furans promoted by carbon dioxide

We report a simple protocol for the transition metal-free, visible-light-driven conversion of 1,3-diketones to tetra-substituted furan skeleton compounds in carbon dioxide (CO2) atmosphere under mild conditions. It was found that CO2could be incorporated at the diketone enolic OH position, which was key to enabling the cleavage of a C-O bond during the rearrangement of a cyclopropane intermediate. This method allows for the same-pot construction of two isomers of the high-value tetra-substituted furan scaffold. The synthetic scope and preliminary mechanistic investigations are presented.

Cobalt(II)-catalyzed electrophilic alkynylation of 1,3-dicarbonyl compounds to form polysubstituted furans via π-π Activation

Polysubstituted furans were obtained with excellent yields via the electrophilic alkynylation of 1,3-dicarbonyl compoundsws with phenyl- or ester-substituted brominated alkynes. The reaction is catalyzed by the inexpensive and readily available catalyst, cobalt(II) chloride, and has a wide substrate scope. The C(sp)-C(sp3) coupling occurs under mild conditions with short reaction times and does not require an inert atmosphere or ligands. It is proposed that the reaction proceeds through a chelation complex of cobalt(II) with the deprotonated 1,3-dicarbonyl compound.

Regioselective synthesis of highly functionalized furans through the RuII-catalyzed [3+2] cycloaddition of diazodicarbonyl compounds

A novel method for the RuII-catalyzed regioselective synthesis of highly functionalized furans from readily available cyclic and acyclic diazodicarbonyl compounds and terminal alkynes is described. The devised protocol offers a straightforward means to the construction of a variety of diverse furan derivatives through powerful cascade processes, including the formation of ruthenium carbenoid, cyclopropenation, ring-opening metathesis, and cyclization. Copyright