54532-12-6 Usage
Chemical class
Derivative of hydrazine
Molecular structure
Complex, composed of a cyclohexylidene group and a dinitrophenyl group attached to the hydrazine molecule
Potential uses
Likely to have uses in chemistry and chemical research
Specific properties and applications
Not readily available
Reactivity
Presence of the tert-butyl and dinitrophenyl groups suggest that the compound may be reactive
Interest for further investigation
Potential reactivity with other chemicals makes it of interest for further investigation in the field of organic chemistry
Check Digit Verification of cas no
The CAS Registry Mumber 54532-12-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,4,5,3 and 2 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 54532-12:
(7*5)+(6*4)+(5*5)+(4*3)+(3*2)+(2*1)+(1*2)=106
106 % 10 = 6
So 54532-12-6 is a valid CAS Registry Number.
54532-12-6Relevant articles and documents
New applications of 1,5-hydrogen atom transfer reactions: Self-oxidizing protecting groups
Curran,Yu
, p. 123 - 127 (2007/10/02)
Three new alcohol protecting groups are introduced: o-bromobenzyl, o-bromo(methylenedioxy)benzyl, and o-bromotrityl. Removal of these protecting groups under reductive conditions with tributyltin hydride is coupled with an oxidation of the substrate to produce directly an aldehyde or ketone. This oxidation occurs by 1,5-hydrogen transfer, followed by β-fragmentation. For example, treatment of the o-bromobenzyl ether of 3-phenyl-1-propanol with tibutyltin hydride at 0.001 M (80°C) directly produces 3-phenyl-1-propanal. An application to the selective oxidation of primary alcohols in the presence of secondary alcohols is also introduced.
