5455-87-8

Basic information

• Product Name: (4-methoxyphenyl)-(4-nitrobenzylidene)amine
• Synonyms: (4-methoxyphenyl)-(4-nitrobenzylidene)amine;N-(4-methoxyphenyl)-1-(4-nitrophenyl)methanimine;(E)-4-Methoxy-N-(4-nitrobenzylidene)aniline
• CAS NO: 5455-87-8
• Molecular Formula: C₁₄H₁₂N₂O₃
• Molecular Weight: 256.25668
• Mol File: 5455-87-8.mol
• Article Data: 62

Chemical Properties

• Boiling Point: 432.1°C at 760 mmHg
• Flash Point: 215.1°C
• Appearance: /
• Density: 1.18g/cm³
• Vapor Pressure: 2.87E-07mmHg at 25°C
• Refractive Index: 1.577
• CAS DataBase Reference: (4-methoxyphenyl)-(4-nitrobenzylidene)amine(CAS DataBase Reference)
• NIST Chemistry Reference: (4-methoxyphenyl)-(4-nitrobenzylidene)amine(5455-87-8)
• EPA Substance Registry System: (4-methoxyphenyl)-(4-nitrobenzylidene)amine(5455-87-8)

Safety Data

• Hazardous Substances Data: 5455-87-8(Hazardous Substances Data)

Usage

Description

(4-methoxyphenyl)-(4-nitrobenzylidene)amine is an organic compound characterized by its chemical formula C14H13N3O3. It is a yellow powder that is primarily utilized in the realms of organic synthesis and chemical research. As an amine, it features a basic nitrogen atom within its structure, which, combined with the presence of a methoxy group and a nitro group, endows the compound with unique reactivity and the capacity to engage in a variety of chemical reactions. This makes (4-methoxyphenyl)-(4-nitrobenzylidene)amine a significant chemical entity with a broad spectrum of potential applications in chemistry and materials science, including the development of pharmaceuticals and other chemical products.

Uses

Used in Organic Synthesis:
(4-methoxyphenyl)-(4-nitrobenzylidene)amine is used as a key intermediate in organic synthesis for the creation of various complex organic molecules. Its unique structure allows it to participate in multiple types of chemical reactions, making it a versatile building block in the synthesis of pharmaceuticals, agrochemicals, and other specialty chemicals.
Used in Chemical Research:
In the field of chemical research, (4-methoxyphenyl)-(4-nitrobenzylidene)amine serves as a valuable compound for studying reaction mechanisms and exploring new synthetic pathways. Its reactivity and structural features provide researchers with opportunities to investigate novel chemical transformations and develop innovative methodologies.
Used in Pharmaceutical Development:
(4-methoxyphenyl)-(4-nitrobenzylidene)amine is used as a precursor in the development of pharmaceuticals. Its potential to be modified and incorporated into larger molecular frameworks makes it a promising candidate for the creation of new drugs with specific therapeutic properties.
Used in Materials Science:
In materials science, (4-methoxyphenyl)-(4-nitrobenzylidene)amine may be employed in the design and synthesis of new materials with unique properties. Its ability to engage in various chemical reactions can contribute to the development of advanced materials for applications in areas such as electronics, coatings, and composites.

InChI:InChI=1/C14H12N2O3/c1-19-14-8-4-12(5-9-14)15-10-11-2-6-13(7-3-11)16(17)18/h2-10H,1H3/b15-10+

Upstream product

• 555-16-8 4-nitrobenzaldehdye 
• 104-94-9 4-methoxy-aniline 
• 105-45-3 acetoacetic acid methyl ester 
• 25174-15-6 (Z)-3-((4-methoxyphenyl)amino)-1-phenylprop-2-en-1-one 
• 100-13-0 4-nitrostyrene 
• 14064-83-6 trans-4-hydroxy-4'-nitrostilbene 
• 2101-87-3 p-methoxy-phenylazide 
• 67-56-1 methanol 
• 62-53-3 aniline 
• 103-82-2 phenylacetic acid 
• 599-67-7 1,1-diphenylethanol 
• 60-12-8 2-phenylethanol 
• 104-88-1 4-chlorobenzaldehyde 
• 126-30-7 2,2-Dimethyl-1,3-propanediol 

Downstream Products

• 64388-22-3 6-methoxy-2-(4-nitrophenyl)quinoline 
• 555-16-8 4-nitrobenzaldehdye 
• 501-58-6 bis(4-methoxyphenyl)diazene 
• 38565-11-6 (4-Methoxy-phenylamino)-(4-nitro-phenyl)-acetonitrile 
• 402740-95-8 (3S,4R)-3-hydroxy-4-(4-methoxyphenylamino)-4-(4-nitrophenyl)-butan-2-one 
• 1133378-54-7 (2S,3S)-1-(4-methoxyphenyl)-2-(4-nitrophenyl)-1,2,3,4-tetrahydropyridine-3-carbaldehyde 
• 1012859-55-0 C₁₅H₁₅N₃O₅ 
• 3156-41-0 1-nitro-4-(2-nitrovinyl)benzene 
• 16035-87-3 N-(p-nitrobenzyl)-p-anisidine 
• 1332344-15-6 (6-methoxy-3-methyl-2-(4-nitrophenyl)-1,2,3,4-tetrahydroquinolin-4-yl)carbamic acid benzyl ester 

Relevant articles and documents

Stereoselective synthesis of a new enantiopure tricyclic β-lactam derivative via a tricarbonyl(η6-arene)chromium(0) complex

The tricyclic β-lactam 5 has been synthesized both in racemic and enantiopure form starting from the enantiomerically pure tricarbonylchromium(0) complex 1. The synthetic sequence involves the stereoselective [2+2] cycloaddition of 1 with acetoxyacetylket

Nanomagnetic catalysis (Fe3O4@S–TiO2): a novel magnetically nano catalyst for the synthesis of new highly substituted tetrahydropyridine derivatives under solvent-free conditions

A novel nanomagnetic catalyst (Fe3O4@S–TiO2) was prepared by the hydrothermal method. At the first, Fe3O4 nanoparticles were synthesized, then iron oxide nanoparticles (IONPs) were dispersed in ethano

Observation of the complex spectra for the supramolecular system involving silver nanoparticles-biaryl Schiff bases containing the nitro group

A series of biaryl Schiff bases containing the nitro groups, 4-XArCH═NArNO2-4′ (XBANO2-4′) and 4-NO2ArCH═NArY-4′ (4-NO2BAY), were synthesized. Also, the fish sperm DNA (fsDNA) and silver nanoparticles (AgNPs) solutions were prepared. By mixing these compounds with fsDNA or AgNPs solution and determining the ultraviolet absorption spectra of the mixture solutions, an interesting phenomenon was found: a new absorption peak λmax,lim appeared in the (XBANO2-4′)-AgNPs solution, which was longer than the wavelength of λmax of XBANO2-4′ solution. The new absorption peak in the (XBANO2-4′)-AgNPs solution was the complex spectrum originating from the electron transfer between XBANO2-4′ and AgNPs. Whereas this phenomenon was not observed in the (4-NO2BAY)-AgNPs solutions, a quantitative correlation analysis was carried out with the measured spectral data, and the results show that the wave number νmax,lim of the λmax,lim is mainly affected by the excited-state substituent constant (Formula presented.) rather than the ground Hammett constant σ of the X group. The redshift magnitude Δνmax,WSL, namely, Δνmax,WSL = (1/λmax) ? (1/λmax,lim), of the wavelength λmax,lim is related to the highest occupied molecular orbital and lowest unoccupied molecular orbital of XBANO2-4′. The discovery of this new phenomenon is helpful to understanding the interaction between AgNPs-organic compound supramolecular systems.