80483-89-2 Usage
Description
22(S),23(S)-Homobrassinolide is a plant hormone belonging to the brassinosteroid family, known for its significant role in regulating plant growth and development. It is characterized by its unique structure, with a 22(S),23(S) configuration, and exhibits high growth-promoting and anti-stress activity.
Uses
Used in Plant Biology Research:
22(S),23(S)-Homobrassinolide is used as a brassinosteroid supplement for studying its effects on various aspects of plant growth and development. It is utilized to investigate its impact on DNA methylation, callus growth, and regeneration in barley, as well as its influence on cell elongation in Arabidopsis thaliana.
Used in Plant Growth and Development Studies:
This brassinosteroid is employed to study its effects on cell division, root germination, and the antioxidant system enzymes in barley. These studies aim to understand the underlying mechanisms of its growth-promoting and anti-stress properties, which can potentially be harnessed to improve crop yields and resilience.
Used in Agriculture:
As a new class of steroidal phytohormones, 22(S),23(S)-Homobrassinolide is used in agriculture for its high growth-promoting and anti-stress activity. It can potentially enhance crop productivity and improve plants' ability to withstand various environmental stresses, making it a valuable tool for sustainable agriculture practices.
Biochem/physiol Actions
22(S),23(S)-Homobrassinolide is a brassinosteroid. It might play a role in the control of plant embryogenesis.
Check Digit Verification of cas no
The CAS Registry Mumber 80483-89-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,0,4,8 and 3 respectively; the second part has 2 digits, 8 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 80483-89:
(7*8)+(6*0)+(5*4)+(4*8)+(3*3)+(2*8)+(1*9)=142
142 % 10 = 2
So 80483-89-2 is a valid CAS Registry Number.
InChI:InChI=1/C29H50O6/c1-7-18(14(2)3)25(32)24(31)15(4)28-23-22(20-13-17(30)10-11-19(20)16(5)35-28)27(34)26(33)21-9-8-12-29(21,23)6/h14-16,18-28,31-34H,7-13H2,1-6H3/t15?,16-,18-,19+,20?,21?,22?,23?,24-,25-,26+,27-,28-,29-/m0/s1
80483-89-2Relevant articles and documents
Toxicity of (22R,23R)-22,23-dihydroxystigmastane derivatives to cultured cancer cells
Misharin, Alexander Yu.,Mehtiev, Arif R.,Zhabinskii, Vladimir N.,Khripach, Vladimir A.,Timofeev, Vladimir P.,Tkachev, Yaroslav V.
, p. 287 - 294 (2010)
Toxicity of eight 22,23-dihydroxystigmastane derivatives (four pairs of (22R,23R)- and (22S,23S)-isomers differing in steroid backbone structure) to human breast carcinoma MCF-7 cells was compared. For every pair of structurally related compounds, (22R,23
SYNTHESIS OF 22S,23S-BRASSINOSTEROIDS BASED ON STIGMASTEROL
Akhrem, A. A.,Lakhvich, F. A.,Khripach, V. A.,Kovganko, N. V.,Zhabinskii, V. N.
, p. 686 - 692 (2007/10/02)
The analogs of 29C-brassinosteroids based on stigmasterol , i.e., 22S,23S-homocastasterone and 22S,23S-homobrassinolide, were synthesized.Electrophilic additions at the Δ22-bond, hydroxylation with osmium tetroxide, and epoxidation followed by conversion of the epoxide into the diol were used for the construction of the 22S,23S-diol grouping.
Synthesis of (22R,23R)-28-Homobrassinolide
Takatsuto, Suguru,Ikekawa, Nobuo
, p. 4181 - 4185 (2007/10/02)
(22R,23R)-28-Homobrassinolide (18), an analog of brassinolide (1), was synthesized from stigmasterol (3).Keywords - brassinolide; plant growth-promoting substance; active analogs of brassinolide; structure-activity relationship; stigmasterol; plant hormones; Baeyer-Villiger oxidation