89836-49-7

Basic information

• Product Name: Quinoline, 6-methyl-3-(phenylmethyl)-
• CAS NO: 89836-49-7
• Molecular Formula: C17H15N
• Molecular Weight: 233.313
• Mol File: 89836-49-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Quinoline, 6-methyl-3-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Quinoline, 6-methyl-3-(phenylmethyl)-(89836-49-7)
• EPA Substance Registry System: Quinoline, 6-methyl-3-(phenylmethyl)-(89836-49-7)

Safety Data

• Hazardous Substances Data: 89836-49-7(Hazardous Substances Data)

Upstream product

• 91-62-3 6-methylquinoline 
• 2785-29-7 benzyl potassium 
• 100-51-6 benzyl alcohol 
• 89816-19-3 2-benzyl-1-(p-methylphenylamino)-3-(p-methylphenylimino)-1-propene 
• 100-39-0 benzyl bromide 
• 4485-91-0 1-(p-methylphenylamino)-3-(p-methylphenylimino)-1-propene 
• 89816-32-0 (E)-2-Benzyl-3-p-tolylamino-propenal 
• 108975-91-3 3-benzyl-6-methyl-1,2,3,4-tetrahydro-quinoline 

Relevant articles and documents

Preparation of 3-Substituted Quinolines. I. Alkylation of Malonaldehyde Dianil Derivatives

2-Substituted 1-arylamino-3-arylimino-1-propenes (III) were prepared by the reaction of N-lithio derivatives of 1-arylamino-3-arylimino-1-propenes (malonaldehyde dianil derivatives) (II) and substituted benzyl bromides. 2-Allyl and 2-(2,4-dinitrophenyl) derivatives of II were prepared by the same method.However, the alkylation failed with less reactive alkyl halides such as ethyl iodide as alkylating agents.Hydrolysis of III afforded α-substituted β-(arylamino)acroleins (IV), which afforded 3-substiuted quinolines (V) on heating with aluminium chloride.Keywords -- 2-alkyl-1-arylamino-3-arylamino-1-propene; α-alkyl-β=(arylamino)acrolein; 3-alkylquinoline; alkylation; hydrolysis; cyclodehydration