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991-84-4

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  • 2,4-Bis(octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine Manufacturer/High quality/Best price/In stock

    Cas No: 991-84-4

  • USD $ 3.0-3.0 / Kilogram

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  • 1-100 Metric Ton/Month

  • Dayang Chem (Hangzhou) Co.,Ltd.
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  • High quality 2,4-bis(octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine supplier in China

    Cas No: 991-84-4

  • No Data

  • 1 Metric Ton

  • 30 Metric Ton/Month

  • Simagchem Corporation
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991-84-4 Usage

Description

2,4-Bis(octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine, also known as Antioxidant 565, is a white crystalline powder that is soluble in many organic solvents but insoluble in water. It is a highly effective antioxidant that can slow or inhibit the oxidation of polymers, preventing them from aging and extending their service life.

Uses

Used in Rubber Industry:
2,4-Bis(octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine is used as an antioxidant for the post-processing and stable treatment of unsaturated rubber. It protects the material from thermal oxidation degradation during production, processing, and final use.
Used in Resin Industry:
2,4-Bis(octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine is used as a resin antioxidant and photothermal stabilizer. It has small addition, low volatility, high color fastness, and can prevent the formation of gel characteristics.
Used in Elastomers:
2,4-Bis(octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine is used as an antioxidant in a variety of elastomers, including polybutadiene (BR), polyisoprene (IR), latex styrene-butadiene rubber (SBR), nitrile rubber (NBR), carboxylate SBR latex (XSBR), and styrene block copolymers such as SBS and SIS.
Used in Adhesives:
2,4-Bis(octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine is used as an antioxidant in hot melt solvent-based adhesives.
Used in Viscosifying Resins:
2,4-Bis(octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine is used as an antioxidant in natural and synthetic viscosifying resins.
Used in Polymers:
2,4-Bis(octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine is used as an antioxidant in various polymers, including EPDM, ABS, impact-resistant polystyrene, polyamide, and polyolefin.

Flammability and Explosibility

Notclassified

Synthesis

By taking 2,6-di-tert-butylphenol as the raw material, and then adding sodium nitrite solution dropwise to form an intermediate product of 2,6-di-tert-butyl-4-nitrosophenol solution, with the added Rayon Nickel is used as a catalyst and carbon monoxide is used instead of hydrogen as a reducing agent to overcome hydrogen as a reducing agent. The pressure in the hydrogenation process is high, which is prone to explosion problems. At the same time, iron crystals are added to remove excess carbon monoxide and avoid the effects of carbon monoxide toxicity. The impurities are removed by filtration, and other by-products will not be formed, which can greatly increase the yield of antioxidant 565, and the product purity is high.

Check Digit Verification of cas no

The CAS Registry Mumber 991-84-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 9,9 and 1 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 991-84:
(5*9)+(4*9)+(3*1)+(2*8)+(1*4)=104
104 % 10 = 4
So 991-84-4 is a valid CAS Registry Number.
InChI:InChI=1/C33H56N4OS2/c1-9-11-13-15-17-19-21-39-30-35-29(36-31(37-30)40-22-20-18-16-14-12-10-2)34-25-23-26(32(3,4)5)28(38)27(24-25)33(6,7)8/h23-24,38H,9-22H2,1-8H3,(H,34,35,36,37)

991-84-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-((4,6-Bis(octylthio)-1,3,5-triazin-2-yl)amino)-2,6-di-tert-butylphenol

1.2 Other means of identification

Product number -
Other names 2,4-Bis(octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Oxidizing/reducing agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:991-84-4 SDS

991-84-4Synthetic route

2,6-di-tert-butyl-4-aminophenol
950-58-3

2,6-di-tert-butyl-4-aminophenol

2,4-dioctylthiol-6-chloro-1,3,5-triazine
978-66-5

2,4-dioctylthiol-6-chloro-1,3,5-triazine

2,6-di-tert-butyl-4-(4,6-bis(octylthio)-1,3,5-triazin-2-ylamino)phenol
991-84-4

2,6-di-tert-butyl-4-(4,6-bis(octylthio)-1,3,5-triazin-2-ylamino)phenol

Conditions
ConditionsYield
In toluene at 60℃; for 5h; Time;42.0 g
2,6-di-tert-butylphenol
128-39-2

2,6-di-tert-butylphenol

2,6-di-tert-butyl-4-(4,6-bis(octylthio)-1,3,5-triazin-2-ylamino)phenol
991-84-4

2,6-di-tert-butyl-4-(4,6-bis(octylthio)-1,3,5-triazin-2-ylamino)phenol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: acetic anhydride; sodium nitrite / methanol; water / 0.5 h / 15 - 30 °C
2: sodium hydroxide; sodium dithionite / water / 1 h / 30 - 65 °C / Inert atmosphere
3: toluene / 5 h / 60 °C
View Scheme
Octanethiol
111-88-6

Octanethiol

2,6-di-tert-butyl-4-(4,6-bis(octylthio)-1,3,5-triazin-2-ylamino)phenol
991-84-4

2,6-di-tert-butyl-4-(4,6-bis(octylthio)-1,3,5-triazin-2-ylamino)phenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrabutylammomium bromide / toluene / Inert atmosphere
2: toluene / 5 h / 60 °C
View Scheme

991-84-4Downstream Products

991-84-4Relevant articles and documents

Synthetic method of antioxidant 565

-

, (2019/04/29)

The invention discloses a synthetic method of an antioxidant 565. The antioxidant 565 refers to 4-[4, 6-dioctyl-1, 3, 5-triazine-2-group] amino]-2, 6-di-tert-butylphenol; acid, 2, 6-di-tert-butylphenol and sodium nitrite are added into an organic solvent for nitrification reaction, and 2,6-ditert-butyl-4-nitrosophenol; sodium hydroxide and a reductant are added, and 2,6-ditert-butyl-4-nitrosophenol has a reduction reaction to generate 2,6-di-tert-butyl-4-aminophenol; n-octyl mercaptan reacts with cyanuric chloride under action of a catalyst to generate a 2,4-dioctyl thiol-6-chlorine-1,3,5-triazine compound; 2,6-ditert-butyl-4-nitrosophenol reacts with the 2,4-dioctyl thiol-6-chlorine-1,3,5-triazine compound to generate 4-[4, 6-dioctyl-1, 3, 5-triazine-2-amino]-2, 6-di-tert-butylphenol. Thesynthesis method avoids the use of an expensive hydrogenation catalyst and dangerous high pressure. The reaction condition is mild, operation is simple, the yield is high, the quality of intermediateproducts is good, and the yield and quality of the prepared 4-[4,6-dioctylthio-1,3,5-triazine-2-group] amino] 2,6-di-tert-butylphenol are higher.

Thioether substituted hydroxybenzophenones and stabilized compositions

-

, (2008/06/13)

2-Hydroxybenzophenone derivatives substituted in the 4′-position by a thioether moiety exhibit enhanced absorption in the UV at longer wavelength. Compositions comprising organic material subject to actinic degradation are beneficially stabilized with such derivatives.

2-(2′-hydroxyphenyl) benzotriazoles containing a 2,4-imidazolidinedione group and process for their preparation

-

, (2008/06/13)

2-(2′-hydroxyphenyl)benzotriazoles having general formula (I). The above 2-(2′-hydroyzphenyl)benzotriazoles having general formula (I) are useful as heat, oxygen and light stabilizers for organic polymers. In particular they are useful as UV stabilizers for organic polymers.

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