Hot Products

Basic Information

Post buying leads

Suppliers

Cas Database

Name	1-(Bromomethyl)naphthalene	EINECS	801-817-2
CAS No.	3163-27-7	Density	1.444 g/cm³
PSA	0.00000	LogP	3.73470
Solubility	Slightly soluble in water.	Melting Point	52-55 °C
Formula	C₁₁H₉Br	Boiling Point	326 °C at 760 mmHg
Molecular Weight	221.096	Flash Point	151.8 °C
Transport Information	N/A	Appearance	off-white powder
Safety	26-36	Risk Codes	20/21/22-36/37/38
Molecular Structure		Hazard Symbols	Xi
Synonyms	Naphthalene, 1-(bromomethyl)-;1-Naphthylmethyl bromide;a-(Bromomethyl)naphthalene;(1-Naphtyl)bromomethane;	Article Data	82

1-(Bromomethyl)naphthalene Synthetic route

: 4780-79-4
1-naphthalene methanol

: 3163-27-7
2-(bromomethyl)naphthalene

Conditions

Conditions	Yield
With bromocyane; triphenylphosphine In dichloromethane at 20℃; Inert atmosphere;	100%
With sulfurous dibromide In toluene for 7h;	99%
With ethyl 2,2-dibromoacetoacetate; triphenylphosphine In dichloromethane at 20℃; for 0.5h;	99%

: 90-12-0
1-Methylnaphthalene

: 3163-27-7
2-(bromomethyl)naphthalene

Conditions

Conditions	Yield
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane	96%
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In benzene at 80℃; for 2.5h; Inert atmosphere;	95%
With N,N,N’,N’-tetrabromobenzene-1,3-disulfonamide; dibenzoyl peroxide In ethyl acetate for 4.5h; Reflux;	90%

: 33250-32-7
1-(dimethoxymethyl)naphthalene

: 3163-27-7
2-(bromomethyl)naphthalene

Conditions

Conditions	Yield
With triethylsilane; Acetyl bromide; tin(II) bromide In dichloromethane at 0℃; for 1h;	96%

: 50-00-0
formaldehyd

: 91-20-3
naphthalene

: 3163-27-7
2-(bromomethyl)naphthalene

Conditions

Conditions	Yield
With hydrogen bromide In acetic acid for 3h; bromomethylation; Irradiation;	92%
With hydrogen bromide; acetic acid at 55 - 60℃;
With hydrogen bromide; acetic acid at 60 - 65℃;

: 66-77-3
1-naphthaldehyde

: 3163-27-7
2-(bromomethyl)naphthalene

Conditions

Conditions	Yield
With isopinocampheyl-boron dibromide dimethylsulfide complex In hexane at 20℃; for 3h; Reduction; bromination;	75%
Multi-step reaction with 2 steps 1: LiAlH4; diethyl ether 2: pyridine; benzene; PBr3 View Scheme
Multi-step reaction with 2 steps 1: sodium tetrahydroborate / methanol / 0.5 h / 20 °C 2: phosphorus tribromide / dichloromethane / 0.5 h / 0 °C View Scheme
Multi-step reaction with 2 steps 1: sodium tetrahydroborate / methanol / 1 h / 0 - 20 °C 2: acetic acid; hydrogen bromide / 0.5 h / 0 °C View Scheme
Multi-step reaction with 2 steps 1: sodium tetrahydroborate / methanol / 1 h / 0 - 20 °C 2: hydrogen bromide / acetic acid / 0.5 h / 0 °C View Scheme

: 90-12-0
1-Methylnaphthalene

A: 6627-78-7
1-bromo-4-methylnaphthalene

B: 3163-27-7
2-(bromomethyl)naphthalene

Conditions

Conditions	Yield
With N-Bromosuccinimide; dibenzoyl peroxide In various solvent(s) at 90 - 95℃; for 1h; Wohl-Ziegler bromination;	A 73% B 3%
With N-Bromosuccinimide at 150℃; under 2625.26 Torr; for 0.0666667h; microwave irradiation;	A 18 % Chromat. B 53 % Chromat.

: 56-23-5
tetrachloromethane

: 128-08-5
N-Bromosuccinimide

: 90-12-0
1-Methylnaphthalene

: 3163-27-7
2-(bromomethyl)naphthalene

: 91-20-3
naphthalene

: 13057-17-5
bromethyl methyl ether

: 3163-27-7
2-(bromomethyl)naphthalene

Conditions

Conditions	Yield
With acetic acid

: 91-20-3
naphthalene

: 3163-27-7
2-(bromomethyl)naphthalene

Conditions

Conditions	Yield
With formaldehyd; sulfuric acid; acetic acid; sodium bromide

N-α-menaphthyl-benzamide: N-α-menaphthyl-benzamide

: 3163-27-7
2-(bromomethyl)naphthalene

Conditions

Conditions	Yield
With phosphorus pentabromide durch Verschmelzen und anschliessendes Destillieren im Vakuum;

1-(Bromomethyl)naphthalene Chemical Properties

IUPAC Name: 1-(Bromomethyl)naphthalene
Synonyms of 1-(Bromomethyl)naphthalene (CAS NO.3163-27-7): Naphthalene, 1-(bromomethyl)- ; 1-Bromomethyl naphthalene ; 1-Bromomethyl naphthalene 99.73% ; (1-Naphtyl)bromomethane ; 1-Naphtylmethyl bromide
CAS NO: 3163-27-7
Molecular Formula: C₁₁H₉Br
Molecular Weight: 221.0932
Molecular Structure:

Melting Point: 52-55°C
Index of Refraction: 1.663
Molar Refractivity: 56.74 cm³
Molar Volume: 153 cm³
Surface Tension: 46.6 dyne/cm
Density of 1-(Bromomethyl)naphthalene (CAS NO.3163-27-7): 1.444 g/cm³
Flash Point: 151.8 °C
Enthalpy of Vaporization: 54.56 kJ/mol
Boiling Point: 326 °C at 760 mmHg
Vapour Pressure: 0.000422 mmHg at 25°C

1-(Bromomethyl)naphthalene Safety Profile

Hazard Codes of 1-(Bromomethyl)naphthalene (CAS NO.3163-27-7): Harmful Xn
Risk Statements: 20/21/22-36/37/38
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 3163-27-7