Basic Information | Post buying leads | Suppliers | Cas Database |
Name |
3-Phenoxybenzyl alcohol |
EINECS | 237-525-1 |
CAS No. | 13826-35-2 | Density | 1.151 g/cm3 |
PSA | 29.46000 | LogP | 2.97120 |
Solubility | insoluble in water | Melting Point |
4-7°C |
Formula | C13H12O2 | Boiling Point | 377.8 °C at 760 mmHg |
Molecular Weight | 200.237 | Flash Point | 151.3 °C |
Transport Information | N/A | Appearance | colourless liquid |
Safety | 26-36/37 | Risk Codes | 22 |
Molecular Structure | Hazard Symbols | Xn, Xi | |
Synonyms |
Benzylalcohol, m-phenoxy- (7CI,8CI);(3-Phenoxyphenyl)methanol;1-Hydroxymethyl-3-phenoxybenzene;3-(Hydroxymethyl)diphenyl ether;3-Phenoxybenzenemethanol;m-Phenoxybenzyl alcohol; |
Article Data | 48 |
3-Phenoxybenzaldehyde
3-Phenoxybenzyl alcohol
Conditions | Yield |
---|---|
With sodium tetrahydroborate In methanol at 0 - 20℃; for 1.5h; | 99% |
With hydrogen In methanol at 20℃; for 4.3h; chemoselective reaction; | 99% |
With sodium tetrahydroborate In tetrahydrofuran; 1,2-dimethoxyethane for 3h; Cooling with ice; | 99.2% |
3-phenoxybenzyl acetate
3-Phenoxybenzyl alcohol
Conditions | Yield |
---|---|
97.2% |
3-Phenoxybenzyl alcohol
Conditions | Yield |
---|---|
With copper dichloride In methanol at 20℃; Hydrolysis; | 95% |
With CuCl2*2H2O In methanol at 20℃; for 1.25h; | 95% |
3-phenoxybenzyl acetate
3-Phenoxybenzyl alcohol
Conditions | Yield |
---|---|
With hydrogenchloride; sodium hydroxide In methanol; dichloromethane; water | 95% |
With hydrogenchloride; sodium hydroxide In methanol; dichloromethane; water | 90% |
With sodium hydroxide In methanol; dichloromethane; water | 90% |
3-phenoxybenzoic acid
3-Phenoxybenzyl alcohol
Conditions | Yield |
---|---|
In ethanol; sulfuric acid; water electrochemical reduction; | 93% |
Multi-step reaction with 3 steps 1: phosphorus (V)-chloride 2: toluene; palladium/barium sulfate 3: concentrated aqueous KOH / 60 °C View Scheme | |
Multi-step reaction with 2 steps 1: sulfuric acid / 3 h / 60 °C 2: methanol; sodium tetrahydroborate / tetrahydrofuran / 0.5 h / Reflux View Scheme |
Conditions | Yield |
---|---|
With sodium chloride; sulfuric acid; sodium hydrogencarbonate; potassium carbonate; copper(I) chloride In chlorobenzene | 93% |
With sodium chloride; sulfuric acid; sodium hydrogencarbonate; potassium carbonate; copper(I) chloride In chlorobenzene |
Conditions | Yield |
---|---|
With potassium phosphate; copper(l) iodide; N1-benzyl-N2-(5-methyl-[1,1'-biphenyl]-2-yl)oxalamide In dimethyl sulfoxide at 120℃; for 24h; Inert atmosphere; | 92% |
With potassium carbonate; 8-quinolinol; copper(l) chloride In various solvent(s) at 150 - 170℃; for 15h; | 88 % Chromat. |
With potassium carbonate; 8-quinolinol; copper(l) chloride In dimethyl sulfoxide at 150 - 170℃; for 15h; Product distribution; solvents varied; | 58 % Chromat. |
Conditions | Yield |
---|---|
With potassium phosphate; copper(l) iodide; N,N’-bis(2-phenylphenyl)oxalic acid In N,N-dimethyl-formamide at 90℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube; | 92% |
3-Hydroxybenzyl alcohol
A
triethylene glucol monomethyl ether
B
3-Phenoxybenzyl alcohol
Conditions | Yield |
---|---|
A n/a B 87% |
Conditions | Yield |
---|---|
With sodium dodecyl-sulfate; potassium carbonate In water at 80℃; under 760.051 Torr; for 10h; Ullmann Condensation; Green chemistry; chemoselective reaction; | 84% |
IUPAC Name: 3-Phenoxybenzyl alcohol
The MF of 3-Phenoxybenzyl alcohol (13826-35-2) is C13H12O2.
The MW of 3-Phenoxybenzyl alcohol (13826-35-2) is 200.23.
Synonyms of 3-Phenoxybenzyl alcohol (13826-35-2): (3-Phenoxyphenyl)methanol ; Benzenemethanol, 3-phenoxy- ; 3-(Hydroxymethyl)diphenyl ether
Product Categories: Benzhydrols,Benzyl & Special Alcohols;Alcohols;Oxygen Compounds
Form: colourless liquid
Index of Refraction: 1.595
EINECS: 237-525-1
Density: 1.151 g/ml
Flash Point: 151.3 °C
Boiling Point: 377.8 °C
Melting Point: 4-7 °C
Water Solubility: Insoluble
BRN: 475312
Stability: Stable
3-Phenoxybenzyl alcohol (13826-35-2) is permethrin, phenothrin and permethrin and other pesticides in the middle of ether, pharmaceutical intermediates.
1. | orl-rat LD50:3 g/kg | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 35 (1)(1991),47. | ||
2. | orl-mus LD50:2040 mg/kg | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 35 (1)(1991),47. | ||
3. | ipr-mus LD50:575 mg/kg | JAFCAU Journal of Agricultural and Food Chemistry. 25 (1977),9. |
Reported in EPA TSCA Inventory.
Moderately toxic by ingestion and intraperitoneal routes. When heated to decomposition it emits acrid smoke and irritating vapors.
Safety information of 3-Phenoxybenzyl alcohol (13826-35-2):
Hazard Codes Xn,Xi
Risk Statements
22 Harmful if swallowed
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37 Wear suitable protective clothing and gloves
WGK Germany 3
RTECS DP0775400
Hazard Note Irritant