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Cas Database

Name	7-Methylindole	EINECS	213-270-1
CAS No.	933-67-5	Density	1.0202
PSA	15.79000	LogP	2.47630
Solubility	negligible	Melting Point	80-84 °C(lit.)
Formula	C₉H₉N	Boiling Point	266 °C(lit.)
Molecular Weight	131.177	Flash Point	266°C
Transport Information	N/A	Appearance	white to slightly beige shiny flakes
Safety	26-36-36/37/39	Risk Codes	36/37/38-36-21/22
Molecular Structure		Hazard Symbols	Xn, Xi
Synonyms	1H-Indole, 7-methyl- (9CI);Indole, 7-methyl- (8CI);7-methyl-1H-indole;7-Methylindol;Indole, 7-methyl-;1H-indole, 7-methyl-;7-Metylindole;	Article Data	56

7-Methylindole Synthetic route

: 65673-86-1
2,3-dihydro-7-methylindole

: 933-67-5
7-methyl-1H-indole

Conditions

Conditions	Yield
With 6C44H32N6O4Ru(2+)12Hf(2+)8O(2-)14HO(1-)6C16H22ClCoN5O6(1-) In 2,2,2-trifluoroethanol; acetonitrile at 20℃; for 12h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Irradiation;	99%
With H8O20P8Pt2(4-)*4C34H72N(1+) In methanol Inert atmosphere; Irradiation;	97%
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; chloropyridinecobaloxime(III) In ethanol at 30℃; for 24h; Inert atmosphere; Schlenk technique; Irradiation;	89%

: 7-methyl-1-pivaloylindole

: 933-67-5
7-methyl-1H-indole

Conditions

Conditions	Yield
With lithium diisopropyl amide In tetrahydrofuran; hexane at 40 - 45℃; for 40h;	93%
With n-butyllithium; diisopropylamine In tetrahydrofuran; hexanes at -78 - 45℃; for 40h; Inert atmosphere;	93%

: 7-methyl-1-tosylindoline

: 933-67-5
7-methyl-1H-indole

Conditions

Conditions	Yield
Stage #1: 7-methyl-1-tosylindoline In tetrahydrofuran at -78℃; for 2h; Stage #2: With oxygen In tetrahydrofuran at 20℃;	84%

: 210536-43-9
6-methyl-2-vinylaniline

: 933-67-5
7-methyl-1H-indole

Conditions

Conditions	Yield
With p-benzoquinone; lithium chloride; dichloro bis(acetonitrile) palladium(II) In tetrahydrofuran for 10h; Heating;	82%

: 637-39-8
triethanolamine hydrochloride

: 95-53-4
o-toluidine

: 933-67-5
7-methyl-1H-indole

Conditions

Conditions	Yield
With triphenylphosphine; tin(ll) chloride; ruthenium trichloride In 1,4-dioxane; water at 180℃; for 20h; Cyclization;	80%
With tin(ll) chloride; ruthenium trichloride; triphenylphosphine In 1,4-dioxane; water at 180℃; for 20h;	80%

: 1428257-94-6
C9H8N2O4

: 933-67-5
7-methyl-1H-indole

Conditions

Conditions	Yield
With indium; acetic acid In benzene at 80℃; for 5h; Inert atmosphere;	76%

: 130103-44-5
7-methyl-1-(phenylsulfonyl)-1H-indole

: 933-67-5
7-methyl-1H-indole

Conditions

Conditions	Yield
With potassium hydroxide In methanol; 1,2-dimethoxyethane for 24h; Heating;	75%

: 548775-76-4
7-methyl-2-trimethylsilanyl-indole-1-carboxylic acid diethylamide

: 933-67-5
7-methyl-1H-indole

Conditions

Conditions	Yield
With potassium hydroxide In ethanol for 12h; Heating;	75%

: 88-72-2
1-methyl-2-nitrobenzene

: 1826-67-1
vinyl magnesium bromide

: 933-67-5
7-methyl-1H-indole

Conditions

Conditions	Yield
In tetrahydrofuran at -45 - -40℃; Cyclization; Bartoli reaction;	71%
In tetrahydrofuran at -40℃; for 0.333333h;	67%
In tetrahydrofuran at -40℃; for 1h; Inert atmosphere;	34%

: 109532-22-1
1-(2-amino-3-methylphenyl)-2-chloroethan-1-one

: 933-67-5
7-methyl-1H-indole

Conditions

Conditions	Yield
With sodium tetrahydroborate In 1,4-dioxane; water for 2h; Heating;	71%

7-Methylindole Chemical Properties

7-Methylindole's Molecular formula: C₉H₉N
7-Methylindole's Molar mass: 131.17
EINECS: 213-270-1
Flash Point: 266°C
Melting point: 80-84 °C(lit.)
Boiling point: 266 °C(lit.)
Water Solubility: negligible
Sensitive: Light Sensitive
Synonyms: 7-Methylindol;Indole, 7-methyl-;7-METHYINDOLE;1H-Indole, 7-methyl-;7-METHYLINDOLE;7-METHYL-1H-INDOLE;7-Methylindole,98%;7-Metlylindole
7-Methylindole is a mildly toxic off-white crystalline organic compound with chemical formula C₉H₉N.

7-Methylindole Uses

7-Methylindole is used in the production of agricultural chemicals and pharmaceuticals.
7-Methylindole is used for organic synthetic reagent.

7-Methylindole Safety Profile

F 13
Hazard Codes Xi,Xn
WGK Germany 3
Risk Statements 36/37/38-36-21/22
Safety Statements 26-36-36/37/39
Hazard Note Light Sensitive/Irritant

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