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Bismuth subcarbonate

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Name

Bismuth subcarbonate

EINECS 227-567-9
CAS No. 5892-10-4 Density 6.86 g/mL at 25 °C(lit.)
PSA 69.67000 LogP -0.16940
Solubility Practically insoluble in water, alcohol. Soluble in nitric acid, hydrochloric acid, concentrated acetic acid.Soluble in mineral acid and glacial acetic acid. Insoluble in water. Melting Point 308(分解)oC
Formula CBi2O5 Boiling Point 333.6oC at 760mmHg
Molecular Weight 509.97 Flash Point 169.8oC
Transport Information N/A Appearance white fine powder
Safety 22-24/25 Risk Codes N/A
Molecular Structure Molecular Structure of 5892-10-4 (Bismuth subcarbonate) Hazard Symbols N/A
Synonyms

Bismuth subcarbonate (TN);Bismuth oxycarbonate;2,4-Dioxa-1,5-dibismapentane,1,3,5-trioxo-;carbonic acid; oxobismuth;Basic bismuth carbonate;Bismuth subcarbonate (JAN/USP);Dibismuth carbonate dioxide;1,3,5-Trioxo-2,4-dioxa-1,5-dibismapentane;

 

Bismuth subcarbonate Specification

The Bismuth subcarbonate, with the CAS registry number 5892-10-4, is also known as 1,3,5-Trioxo-2,4-dioxa-1,5-dibismapentane. It belongs to the product category of Inorganics. Its EINECS number is 227-567-9. This chemical's molecular formula is CBi2O5 and molecular weight is 509.97. What's more, its systematic name is bis(oxobismuthanyl) carbonate. Its classification code is Protectant [topical]. It should be sealed and stored in a cool and dry place. Moreover, it should be protected from light and moisture. It is used in pharmaceutical industry, and it can also be used as an analytical reagent or to prepare bismuth salts. You should not breathe dust. When using it, you must avoid contact with eyes. 

Physical properties of Bismuth subcarbonate are: (1)#H bond acceptors: 5; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 4; (4)Polar Surface Area: 69.67 Å2.

Preparation: this chemical can be prepared by nitric acid bismuth as raw materials, which then has a metathesis reaction with sodium carbonate solution. Then after washing, centrifugal separation, drying, smashing, the end product Bismuth subcarbonate is got.

6 Bi(NO3)3 + 4 Na2CO3 + H2O → (BiO)2CO3·1/2H2O + Na2CO3 + 4 CO2

You can still convert the following datas into molecular structure:
(1)SMILES: C(=O)(O[Bi]=O)O[Bi]=O
(2)Std. InChI: InChI=1S/CH2O3.2Bi.2O/c2-1(3)4;;;;/h(H2,2,3,4);;;;/q;2*+1;;/p-2
(3)Std. InChIKey: MGLUJXPJRXTKJM-UHFFFAOYSA-L 

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