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Name |
Bismuth nitrate oxide |
EINECS | 233-792-3 |
CAS No. | 10361-46-3 | Density | 4.93 |
PSA | 419.34000 | LogP | -0.98120 |
Solubility | Insoluble in water. Soluble in acids. | Melting Point |
260, decomposing [HAW93] |
Formula | BiNO4 | Boiling Point | 83oC at 760 mmHg |
Molecular Weight | 286.985 | Flash Point | N/A |
Transport Information | UN 1477 | Appearance | White powder |
Safety | 17-26-36/37/39 | Risk Codes | 8-36/37/38 |
Molecular Structure | Hazard Symbols | O, Xi | |
Synonyms |
Bismuthnitrate (BiO(NO3)) (6CI);Bismuth nitrate oxide (BiO(NO3)) (7CI,8CI);Bismuthine, (nitrooxy)oxo- (9CI);Bismuth nitrate oxide(Bi(NO3)O); |
Article Data | 16 |
Conditions | Yield |
---|---|
In nitric acid aq. HNO3; formation of the sparingly soluble basic salts; solution of the salts if H(1+)-activity exceeds 0.06;; | |
In nitric acid aq. HNO3; formation of the sparingly soluble basic salts; solution of the salts if H(1+)-activity exceeds 0.06;; |
bismuth subnitrate
Conditions | Yield |
---|---|
In neat (no solvent) drying over H2SO4 or in a stream of CO2 or dry air to constant weight;; | |
In neat (no solvent) storage of the pentahydrate in a desiccator until 19 % loss of weight, then heating at 50-100°C in a dry stream of air without melting;; constant weight after 6 days;; |
A
bismuth subnitrate
Conditions | Yield |
---|---|
With H2O In nitric acid aq. HNO3; slow diffusion of H2O into a saturated solution of Bi nitrate in HNO3;; separation of different crystals;; |
Conditions | Yield |
---|---|
In nitric acid dissoln. in dild. HNO3 (excess); addn. of H2O; pptn.;; | |
In nitric acid aq. HNO3; dissoln. in dild. HNO3 (excess); addn. of H2O; pptn.;; |
Conditions | Yield |
---|---|
In nitric acid boiling with a small amt. of concd. HNO3; evapn.;; | |
In nitric acid aq. HNO3; boiling with a small amt. of concd. HNO3; evapn.;; |
bismuth subnitrate
Conditions | Yield |
---|---|
In neat (no solvent, solid phase) byproducts: N2O5; heating at 440-500°C; |
Conditions | Yield |
---|---|
With water In nitric acid byproducts: N oxide; preparation of a layer of 165 g remolten Bi (description of method given) and solvation at 60-70°C in 1040 ml 25% HNO3; vigorous reaction, form. of N oxide; filtration and evaporation in porcelain crucibles; addition of 800 ml H2O under stirring;; addition of the mass to hot water and washing the precipitate with H2O; drying with alcohol and heating at 45°C;; | |
With H2O In nitric acid byproducts: N oxide; aq. HNO3; preparation of a layer of 165 g remolten Bi (description of method given) and solvation at 60-70°C in 1040 ml 25% HNO3; vigorous reaction, form. of N oxide; filtration and evaporation in porcelain crucibles; addition of 800 ml H2O under stirring;; addition of the mass to hot water and washing the precipitate with H2O; drying with alcohol and heating at 45°C;; |
bismuth
bismuth subnitrate
Conditions | Yield |
---|---|
With nitric acid In nitric acid byproducts: NO; Bi metal was dissolved in 11 M HNO3; evapd. to dryness, baked at 115°C for several h, elem. anal.; |
basic bismuth nitrate
bismuth subnitrate
Conditions | Yield |
---|---|
In neat (no solvent) dehydration;; | |
In neat (no solvent) heating in a dry stream of CO2 at 100°C for 6 hours with formation of Bi2O3*N2O5*H2O and finally with formation of Bi2O3*N2O5;; |
bismuth subnitrate
Conditions | Yield |
---|---|
In neat (no solvent) dehydration;; |
Molecular Structure:
Molecular Formula: BiNO4
Molecular Weight: 286.9847
IUPAC Name: Oxobismuthanyl nitrate
Synonyms of Bismuth nitrate oxide (CAS NO.10361-46-3): EINECS 233-792-3 ; (Nitrooxy)oxobismuthine
CAS NO: 10361-46-3
Product Categories: Inorganic Chemicals ; API's
H bond acceptors: 4
H bond donors: 1
Polar Surface Area: 66.05 Å2
Enthalpy of Vaporization: 37.72 kJ/mol
Boiling Point: 83 °C at 760 mmHg
Vapour Pressure: 49.8 mmHg at 25°C
Bismuth nitrate oxide (CAS NO.10361-46-3) is used in treating the stomach and duodenal ulcer and the diarrhea.
Hazard Codes of Bismuth nitrate oxide (CAS NO.10361-46-3): O,Xi
Risk Statements: 8-36/37/38
R8: Contact with combustible material may cause fire.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 17-26-36/37/39
S17: Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 1477 5.1/PG 2
WGK Germany: 3
F: 8
HazardClass: 5.1
PackingGroup: II