Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Boroxin,2,4,6-triphenyl-

Related Products

Hot Products

Name

Boroxin,2,4,6-triphenyl-

EINECS N/A
CAS No. 3262-89-3 Density 1.13 g/cm3
PSA 27.69000 LogP 1.23600
Solubility N/A Melting Point 217.0 to 221.0 °C
Formula C18H15B3O3 Boiling Point 368.3 °C at 760 mmHg
Molecular Weight 311.748 Flash Point 176.6 °C
Transport Information N/A Appearance N/A
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 3262-89-3 (TRIPHENYLBOROXIN) Hazard Symbols N/A
Synonyms

2,4,6-Triphenylboroxin;Benzeneboronic anhydride;Cyclic benzeneboronic anhydride;Cyclic phenylboronic anhydride;Phenylboronic acid anhydride;Phenylboronic anhydride;Triphenylboroxin;Triphenylboroxole;

Article Data 161

Boroxin,2,4,6-triphenyl- Synthetic route

98-80-6

phenylboronic acid

3262-89-3

triphenylboroxine

Conditions
ConditionsYield
at 110℃; for 6h;100%
at 110℃; for 6h; Inert atmosphere; Neat (no solvent);100%
Stage #1: phenylboronic acid With barium(II) hydroxide In water at 80℃; for 0.0833333h;
Stage #2: With Au38(SCH2CH2Ph)24 In toluene at 80℃; for 12h; Reagent/catalyst;
100%
357417-22-2

N-(4-chlorobenzylidene)-4-methylbenzenesulfonamide

98-80-6

phenylboronic acid

3262-89-3

triphenylboroxine

Conditions
ConditionsYield
In toluene for 12h; Dean-Stark; Reflux;99%

boron trioxide

960-71-4

triphenylborane

3262-89-3

triphenylboroxine

Conditions
ConditionsYield
In neat (no solvent) refluxing equimolar amounts for 48h;; dissolving in CCl4,;91%
In neat (no solvent)
591-50-4

iodobenzene

98-80-6

phenylboronic acid

A

3262-89-3

triphenylboroxine

B

92-52-4

biphenyl

Conditions
ConditionsYield
With potassium carbonate In ethanol at 78℃; for 1h; Catalytic behavior; Reagent/catalyst; Suzuki-Miyaura Coupling;A n/a
B 87%
With potassium carbonate In ethanol at 78℃; for 1h; Suzuki-Miyaura Coupling;A 49%
B 6%
13292-87-0

dimethylsulfide borane complex

108-95-2

phenol

3262-89-3

triphenylboroxine

Conditions
ConditionsYield
With water; pyridin-2-ylmethyl methanesulphonate In tetrahydrofuran; toluene at 90℃; for 0.666667h; Temperature; Inert atmosphere;80.26%
7397-50-4

diphenyl(diethylamino)borane

7360-71-6

N,N'-Bis-(diphenylboryl)-hydrazin

101550-01-0

(n-C4H9)2BNHNC6H5B(n-C4H9)2

3262-89-3

triphenylboroxine

Conditions
ConditionsYield
byproducts: (C6H5)2CNNC(C6H5)2; 80°C, reflux, 1.5 h;75%
byproducts: (C6H5)2CNNC(C6H5)2; 80°C, reflux, 1.5 h;75%
18885-85-3

2-phenyl-4H-benzo-1,3,2-dioxaborine

A

3262-89-3

triphenylboroxine

B

100152-08-7

9',9'A-dihydro-4'aH-spiro[chroman-2,1'-xanthen]-2'-one

C

136352-96-0

C28H24O4

Conditions
ConditionsYield
at 900℃; under 0.005 Torr;A 70%
B 12%
C 31%
110-85-0

piperazine

98-80-6

phenylboronic acid

A

3262-89-3

triphenylboroxine

B

92-54-6

4-phenyl-1-piperazine

C

92-52-4

biphenyl

Conditions
ConditionsYield
With [Cu4I4(1,4-diazabicyclo[2.2.2]octane)2]n In methanol at 27℃; for 5h;A 9 %Chromat.
B 68%
C 20 %Chromat.
1309575-95-8

2,4-diphenylbenzo[j]-9-methyl-8-aza-1,3,5,2,4-trioxadiboracycloundec-8-ene

A

3262-89-3

triphenylboroxine

B

1309575-94-7

(rac)-2-(phenyl)benzo[j]-7-methyl-6-aza-1,3-dioxa-2-boracyclononen-6-ene

Conditions
ConditionsYield
In toluene for 24h; Reflux; diastereoselective reaction;A n/a
B 60%
1309575-95-8

2,4-diphenylbenzo[j]-9-methyl-8-aza-1,3,5,2,4-trioxadiboracycloundec-8-ene

98-80-6

phenylboronic acid

A

3262-89-3

triphenylboroxine

B

1309575-94-7

(rac)-2-(phenyl)benzo[j]-7-methyl-6-aza-1,3-dioxa-2-boracyclononen-6-ene

Conditions
ConditionsYield
In toluene soln. of C6H4C(CH3)N(C2H4OB(C6H5)O)B(C6H5) refluxed for 24 h; solvent and water eliminated, residue washed with CH3Cl, recrystd. from chloroform; elem. anal.;A n/a
B 60%

Boroxin,2,4,6-triphenyl- Specification

The Boroxin,2,4,6-triphenyl-, with the CAS registry number 3262-89-3, is also known as Cyclic benzeneboronic anhydride. It belongs to the product category of Organometallics. This chemical's molecular formula is C18H15B3O3 and molecular weight is 311.74. What's more, its IUPAC name is 2,4,6-Triphenyl-1,3,5,2,4,6-trioxatriborinane. It is stable at room temperature and pressure, and it should be stored in a cool and dry place and be protected from light.

Physical properties of Boroxin,2,4,6-triphenyl- are: (1)#H bond acceptors: 3; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 3; (4)Polar Surface Area: 27.69 Å2; (5)Index of Refraction: 1.564; (6)Molar Refractivity: 89.77 cm3; (7)Molar Volume: 275.6 cm3; (8)Polarizability: 35.58×10-24 cm3; (9)Surface Tension: 38.1 dyne/cm; (10)Density: 1.13 g/cm3; (11)Flash Point: 176.6 °C; (12)Enthalpy of Vaporization: 59.08 kJ/mol; (13)Boiling Point: 368.3 °C at 760 mmHg; (14)Vapour Pressure: 2.72E-05 mmHg at 25 °C.

Preparation: this chemical can be prepared by 2-phenyl-4H-benzo[1,3,2]dioxaborinine at the temperature of 900 °C. The yield is about 12%.

Boroxin,2,4,6-triphenyl- can be prepared by 2-phenyl-4H-benzo[1,3,2]dioxaborinine at the temperature of 900 °C.

Uses of Boroxin,2,4,6-triphenyl-: it can be used to produce 4-nitro-biphenyl at the temperature of 65 °C. It will need reagent K2CO3 and solvents acetone, H2O with the reaction time of 45 min. This reaction will also need catalyst palladium acetate. The yield is about 97%.

Boroxin,2,4,6-triphenyl- can be used to produce 4-nitro-biphenyl at the temperature of 65 °C.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: B1(OB(OB(O1)C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4
(2)InChI: InChI=1S/C18H15B3O3/c1-4-10-16(11-5-1)19-22-20(17-12-6-2-7-13-17)24-21(23-19)18-14-8-3-9-15-18/h1-15H
(3)InChIKey: VOXXGUAZBWSUSS-UHFFFAOYSA-N

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 3262-89-3