- Electro-oxidative Intermolecular Allylic C(sp3)-H Aminations
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The oxidative intermolecular nitrogenation of C(sp3)-H bonds represents one of the most straightforward strategies to construct nitrogen-containing molecules. However, a sacrificial chemical oxidant is generally required. Herein, we describe el
- Wang, Yulei,Lin, Zhipeng,Oliveira, Jo?o C. A.,Ackermann, Lutz
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p. 15935 - 15945
(2021/06/28)
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- Direct substitution of the hydroxy group with highly functionalized nitrogen nucleophiles catalyzed by Au(III)
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A direct catalytic substitution of various allylic and benzylic alcohols with synthetically useful, but acid-sensitive Boc, Bus, and Dios protected amine nucleophiles, which have not been well utilized for Lewis acid catalysis, with various functionalities (OTBS, OTHP, etc.) was efficiently catalyzed by 1 mol% of Au(iii) under mild conditions.
- Ohshima, Takashi,Nakahara, Yasuhito,Ipposhi, Junji,Miyamoto, Yoshiki,Mashima, Kazushi
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supporting information; experimental part
p. 8322 - 8324
(2011/09/15)
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