cas 215054-80-1, (S)-2-AMINO-5-(1,3-DIOXOLAN-2-YL)-PENTANOIC ACID | Articles data ｜lookchem

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215054-80-1

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The combination of hydroformylation and biocatalysis for the large-scale synthesis of (S)-allysine ethylene acetal
The compound, (S)-2-amino-5-[1,3]dioxolan-2-yl-pentanoic acid [(S)-allysine ethylene acetal], is a key intermediate in a number of angiotension-I converting enzyme (ACE) and neutral endopeptidase (NEP) inhibitors currently in clinical trials. Through a co
Cobley, Christopher J.,Lloyd, Michael C.,Simmonds, Shaun,Hanson, Christopher H.,Peng, Wei Jun
experimental part
p. 284 - 290
(2011/10/02)

Method for producing L-Allysine acetal
A method for producing L-allysine acetal represented by general formula (II), comprising reacting D,L-allysinamide acetal represented by general formula (I) with cells of microorganism or treated cell product having an activity of stereoselectively hydrolyzing L-allysinamide acetal, wherein R1and R2, which may be the same or different, each independently represent a lower alkyl group, or R1and R2are combined to form an alkylene group represented by [CH2]n, and n is 2 to 3. D,L-allysinamide acetal represented by general formula (I) is also in the scope of the invention. According to the present invention, L-allysine acetal useful as a raw material for medicine can be produced in a smaller number of steps at low costs.
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(2008/06/13)

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N-benzoyl allysine ethylene acetal

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Chemical Properties

Melting Point: >200 °C (decomp)
Boiling Point: 338.72 °C at 760 mmHg
Flash Point:158.653 °C
Density: 1.208 g/cm³
PKA: 2.53±0.24(Predicted)
PSA: 81.78000
LogP: 0.64180

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