- Polyfluoroalkyl chlorosulfites as new polyfluorinating agents
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The interaction of polyfluorinated alcohols with triethylamine and the kinetics of the reaction of the resulting triethylamine complexes with thionyl chloride were studied, the mechanism of formation of polyfluoroalkyl chlorosulfites was considered, and the optimal reaction conditions were found. The alkylating power of polyfluoroalkyl chlorosulfites was studied in reactions with alkali metal halides (to obtain polyfluorohaloalkanes), in synthesis of acrylic and methacrylic acid esters, and in synthesis of polyfluoroalkyl ethers (with polyfluoroalkyl 1-adamantyl ethers as example).
- Rakhimov,Vostrikova
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- EXTERNAL PREPARATION FOR THE SKIN AND COPOLYMER TO BE USED THEREIN
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An object of the present invention is to provide an external preparation for the skin, which shows an excellent effect of sufficiently protecting the living body against irritants that exist in the external environments, and a polymer material to be preferably used therein. Provided is an external preparation for the skin obtained mixing a copolymer which comprises constituent units derived from monomers of the general formula (I), (II) and, if necessary, (IV) with the content of units (I) ranging from 5 to 25 wt % based on the total amount of all the constituent units, preferably with the contents of units (I), (II) and (IV) being 5 to 9.8 wt %, 30.2 to 45 wt %, and 50 to 60 wt %respectively, with other optional components. In the formula, R1 is H or C1-3 alkyl; R2 is C5-12 alkyl having 8 to 21 fluorine atoms; R3 is H or C1-3 alkyl; R4 is optionally hydroxylated C2-4 alkylene; R5 is H, a C1-20 aromatic group, a C1-20 aliphatic hydrocarbon group, or C1-20 acyl; and n is 4 to 50.
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Page/Page column 9
(2008/06/13)
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- SYNTHESIS AND PHYSICOCHEMICAL PROPERTIES OF ORGANOFLUORINE ESTERS OF ACRYLIC, METHACRYLIC, AND MALEIC ACIDS.
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The purpose of this work is to synthesize, and to study the physicochemical properties of organofluorine acrylates, methacrylates, and maleates.
- Gol'din,Averbakh,Nekrasova,Lavygin,Leitan,Chalbysheva
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p. 1244 - 1247
(2007/10/02)
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