cas 2439-55-6, N-METHYL-N-OCTADECYLAMINE | Articles data ｜lookchem

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2439-55-6

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Photochemical Cleavage of Benzylic C-N Bond to Release Amines
The 3-(diethylamino)benzyl (DEABn) group has been studied for releasing primary, secondary, and tertiary amines by direct photochemical breaking of the benzylic C-N bond. While photochemical release of primary and secondary amines provides high yields in
Wang, Pengfei,Devalankar, Dattatray A.,Lu, Wenya
p. 6195 - 6200
(2016/08/16)

Cleavage of a p-cyanobenzyl group from protected alcohols, amines, and thiols using triethylgermyl sodium
Alcohols, amines, and thiols protected with a p-cyanobenzyl group can be easily and quantitatively deprotected using triethylgermyl sodium under mild conditions.
Yokohama, Yasuo,Takizawa, Shuichi,Nanjo, Masato,Mochida, Kunio
p. 1032 - 1033
(2007/10/03)

Kinetics of Reversible Endothermic Elimination Reactions: β-Amino Carboxylic Esters and Amides
The kinetics of the elimination reactions of substituted β-amino carboxylic esters and amides, to give amines and the α,β-unsaturated esters and amides, have been studied in several model systems.The reaction was studied by trapping the olefin formed with another nucleophile capable of competing with the amine formed by elimination.The rate constant for elimination of methyl 3-(N-methyl-N-butylamino)propionate, in methanol at room temperature, is 1.8E-6 s-1.The corresponding amide has an elimination rate constant 8.8E-8 s-1.Rate constants for the forward reaction were also measured and combined with the reversion rate constants to yield equilibrium constants for the same two systems.The equilibrium constants for the methyl esters is 2.0E4 L mol-1 and for the amides is 7.3E3 L mol-1.These were confirmed by measurement of the equilibrium concentrations of olefins by 1H NMR spectroscopy.
Johnson, Mark R.
p. 833 - 837
(2007/10/02)

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Chemical Properties

Melting Point: 42-46 °C(lit.)
Boiling Point: 332°Cat760mmHg
Flash Point:142.7°C
Density: 0.807g/cm³
Solubility:soluble in Methanol
Vapor Pressure: 0.000151mmHg at 25°C
Refractive Index: 1.4528 (estimate)
PKA: 10.78±0.10(Predicted)
BRN: 1758431
PSA: 12.03000
LogP: 6.85820

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