- Nitrogen-containing heterocycles from metal β-diketonates
-
Factors determining the reaction of metal β-diketonates with hydrazine, in particular the nature of central metal ion and structure of β-diketonate ligand, are discussed. The possibility for the preparation of other heterocyclic compounds via reaction of metal acetylacetonates with phenylhydrazine, o-phenylenediamine, urea, and thiourea was studied.
- Svistunova,Shapkin,Nikolaeva,Apanasenko
-
experimental part
p. 756 - 761
(2011/08/06)
-
- Reactions of copper(II) β-diketonates under free radical conditions. Preparation of highly congested β-diketones
-
Copper(II) β-diketonates react with alkyl bromides under free radical conditions to give highly congested β-diketones such as 3-(1-adamantyl)-3-alkylpentane-2,4-diones. Another typical free radical reagent: benzoyl peroxide, reacts also functionalizing the intercarbonyl positions.
- Lloris, Maria E.,Galvez, Nicanor,Marquet, Jorge,Moreno-Manas, Marcial
-
p. 8031 - 8042
(2007/10/02)
-