- Nitrogen-containing compound, application and organic light-emitting device using nitrogen-containing compound
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The present invention relates to a nitrogen-containing compound. The nitrogen-containing compound has a structure with a formula (1) or a formula (2) which is described in the specification. In the formula (1) and the formula (2), Ar is selected from the
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Paragraph 0089; 0100-0106
(2020/05/02)
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- Fine tuning of emission color of iridium(iii) complexes from yellow to red via substituent effect on 2-phenylbenzothiazole ligands: Synthesis, photophysical, electrochemical and DFT study
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Four novel iridium(iii) complexes bearing biphenyl (7a-7c) or fluorenyl (7d) modified benzothiazole cyclometallate ligands are synthesized. In comparison with the yellow parent complex, bis(2-phenylbenzothiozolato-N,C 2′) iridium(iii) (acetylacetonate) [(pbt)2Ir(acac)] (λPLmax = 557 nm, φPL = 0.26), 7a-7d show 20-43 nm bathochromic shifted orange or red phosphorescence in solution, with maximum photoluminescence (PL) quantum yield of 0.62, and PL lifetime of 1.8-2.0 μs. Meanwhile, the resulting complexes also exhibit intense orange or red phosphorescence of λPLmax = 588-611 nm in solid films. The complex 7c with two tert-butyl substituents possesses the highest phosphorescent efficiency both in dilute solution and thin solid films, therefore may be a prospective candidate for both doping and host emitting electrophosphorescent material. Furthermore, despite the observation of severe oxygen quenching for 7a-7d in solution, 7a and 7c even show efficient emission intensity quenching by oxygen in their solid state due to the existence of void channels in crystals; consequently, they are promising molecular oxygen sensor reagents. Electrochemical measurement and DFT calculation results suggest that all these chelates own declined LUMOs of 0.1 eV relative to that of (pbt) 2Ir(acac) owing to the contribution of the phenyl substituents; whereas only 7d shows a more destabilized HOMO (~0.1 eV) compared with the parent chelate.
- Li, Ming,Zeng, Hui,Meng, Yanyan,Sun, Huiqin,Liu, Song,Lu, Zhiyun,Huang, Yan,Pu, Xuemei
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p. 7153 - 7164
(2011/09/12)
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- BLUE LIGHT-EMITTING COMPOUND, METHOD FOR PRODUCING SAME AND LIGHT-EMITTING DEVICE UTILIZING SAME
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The present invention provides blue-light emitting compounds capable of emitting blue light at a high luminance for a long time upon the application of electric energy, processes of producing the compounds, and luminescent elements including the blue light-emitting compounds. One of the compounds according to the present invention is characterized by the chemical structure represented by formula (1).
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Page/Page column 31
(2008/06/13)
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