Synthesis and coordinative properties of a hybrid bis(diphenylphosphino)methane-terpyridine
A newly-synthesized 4'-[bis(diphenylphosphino)methane]2,2':6',2''- terpyridine-based (dppm-terpy) ligand forms complexes by selective complexation of the terpy or diphos segment, respectively, with Fe(II) or Pd(II) salts; in the latter case, an X-ray stru
Pickaert, Guillaume,Cesario, Michele,Douce, Laurent,Ziessel, Raymond
Photoactive molecular-scale wires: Synthesis of carotene/terpyridine ditopic ligands
We report the preparation of multi-component molecules based on carotene-substituted 2,2':6',6-terpyridine ligands. The synthetic protocol based on a double Wittig-Horner coupling reaction uses 4'- methyldiphenylphosphinoxide-2,2':6',2-/s
Pickaert, Guillaume,Ziessel, Raymond
p. 3497 - 3500
(2007/10/03)
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