- Compound for molecular electronic device having thiol anchoring group, method of synthesizing the compound, and molecular electronic device having molecular active layer obtained from the compound
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Provided are a compound for a molecular electronic device which includes a terpyridine-ruthenium organic metal compound including a thiol anchoring group of the formula below, a method of synthesizing the compound and a molecular electronic device including a molecular active layer obtained from the compound. In the formula, R1 and R2 are each a thioacetyl group or a hydrogen atom, at least one of R1 and R2 is a thioacetyl group, and m and n are each integers from 0 to 20. The molecular active layer, which is formed by self-assembling the compound on an electrode surface, composes a switching element and a memory element.
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Page/Page column 8; sheet 2/18
(2008/12/08)
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- An efficient and easy route to trimethyl derivatives of 2,2':6',2''-terpyridine
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By using the Stille coupling reaction, trimethyl derivatives of 2,2':6',2''-terpyridine have been prepared in good yields.
- Fallahpour
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p. 1665 - 1667
(2007/10/03)
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- Bucky ligands: Synthesis, Ruthenium(II) complexes, and electrochemical properties
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The novel tridentate 2,2':6',2-terpyridine ligand (1) in which the metal-binding domain is directly attached to a methanofullerene C60 unit was incorporated into ruthenium-based diads and triads that may undergo photoinduced charge s
- Armspach, Dominique,Constable, Edwin C.,Diederich, Fran?ois,Housecroft, Catherine E.,Nierengarten, Jean-Fran?ois
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p. 723 - 733
(2007/10/03)
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- Amphiphilic Terpyridine Complexes of Ruthenium and Rhodium displaying Lyotropic Mesomorphism
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New 4'-alkyl-substituted 2,2':6',2''-terpyridine (4'R-terpy) compounds have been synthesised from 4'-methyl-2,2':6',2''-terpyridine and an appropriate 1-bromoalkane and complexed with ruthenium and rhodium to yield new bis(terpyridine) complexes (2+) (R = C19H39 or C31H63) and (3+) (R = C19H39) as chloride and hexafluorophosphate salts.These complexes are amphiphilic being structurally related to surfactant tris(bipyridine)ruthenium complexes.Both ruthenium and rhodium complexes with R = C19H39 and chloride counter ions show lyotropic mesomorphism in water, and the ruthenium complex with R = C31H63 shows mesophase formation in ethylene glycol.
- Holbrey, John D.,Tiddy, Gordon J. T.,Bruce, Duncan W.
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p. 1769 - 1774
(2007/10/02)
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- Photoinduced electron- and energy-transfer processes occurring within porphyrin-metal-bisterpyridyl conjugates
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Photophysical properties have been measured for zinc and free-base porphyrins covalently linked to ruthenium-(II) or rhodium(III) bisterpyridyl complexes using ultrafast transient absorption spectroscopy. The appended metal complex quenches porphyrin fluo
- Collin, Jean-Paul,Harriman, Anthony,Heitz, Valérie,Odobel, Fabrice,Sauvage, Jean-Pierre
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p. 5679 - 5690
(2007/10/02)
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- Highly coupled two-component systems consisting of porphyrins attached to a rhodium(III) bis-terpyridine complex
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A 2,2′,6′,2″-terpyridine (terpy) ligand bearing a porphyrin unit at its 4′ position has been made as well as the corresponding rhodium(III) bis-terpy complex. The porphyrin site can be metallated by zinc(II).
- Odobel, Fabrice,Sauvage, Jean-Pierre,Harriman, Anthony
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p. 8113 - 8116
(2007/10/02)
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- A NEW SYNTHESIS OF PIPERIDINES AND PYRIDINES: ANNULATION OF 2-AZAALLYL ANIONS
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A one-pot approach to 6-membered heterocyclic rings combines two 1,3-dipole equivalents: 2-azaallyl anions(2) and iodosilane 3.The resulting cis-2,6-disubstituted 4-methylenepiperidines are converted in high yield to 2,4,6-trisubstituted pyridines (6) by oxidation with mercuric acetate in acetic acid.
- Bell, Thomas W.,Hu, Lain-Yen
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p. 4819 - 4822
(2007/10/02)
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- 4-Vinyl-, 6-Vinyl-, and 4'-Vinyl-2,2':6',2''-terpyridinyl Ligands: Their Synthesis and the Electrochemistry of Their Transition-Metal Coordination Complexes
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4'-Vinyl-2,2':6',2''-terpyridinyl was conveniently prepared from 2-acetylpyridine via α-oxoketene dithioacetal methodology, the intermediate 4'-(methylthio)-2,2':6',2''-terpyridinyl being converted into the corresponding 4'-methyl derivative with methylma
- Potts, Kevin T.,Usifer, Douglas A.,Guadalupe, Ana,Abruna, Hector D.
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p. 3961 - 3967
(2007/10/02)
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