cas 35206-02-1, 7-(2-aminoethyl)-3,7-dihydro-1,3-dimethyl-1H-purine-2,6-dione | Articles data ｜lookchem

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35206-02-1

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Nucleophilic ring opening of aziridines
This account of research work on nucleophilic ring opening (NRO) of aziridines (Az's) demonstrates the broad synthetic scope of this reaction, inclusive secondary reactions, and it discusses the special mechanistic fundamentals and details as well as mechanistic variants. Formation of a C-C bond by NRO is the red thread in this report. A central mechanistic aspect is the quality of the leaving group in Az bases, aziridinium ions and activated Az's (acyl, sulfonyl; double activation). Factors controlling the regioselectivity of NRO are dealt with as well as the influence of the nitrogen pyramid. Competing reactions include carbonyl attack (acylated Az's) and electron transfer with cases of pseudo-NRO (multistep radical paths). Wiley-VCH Verlag GmbH, 1999.
Stamm, Helmut
p. 319 - 331
(2007/10/03)

7-Substituted theophyllines. Part I - Nicotinamido derivatives
-
Duranti,Bonifazi,Balsamini,Peruzzi,Lombardelli
p. 284 - 291,285, 286
(2007/10/04)

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Chemical Properties

Melting Point: 187-190 °C
Boiling Point: 470.7°Cat760mmHg
Flash Point:238.5°C
Density: 1.51g/cm³
Vapor Pressure: 4.96E-09mmHg at 25°C
PKA: 9.02±0.10(Predicted)
PSA: 87.84000
LogP: -0.90730

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