- Preparing method of environment-friendly azo dispersing dyestuff
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The invention provides a preparing method of environment-friendly azo dispersing dyestuff. The preparing method comprises a diazotization reaction and a coupling reaction, wherein auxiliaries of ferric trichloride, hydrogen peroxide and sodium hypobromite are added in the coupling reaction system. 23 kinds of harmful aromatic amine, benzene containing chlorine, methylbenzene containing chlorine and phenol containing chlorine contained in the dyestuff prepared according to the method are greatly lowered, in this way, the dyestuff conducts dyeing, and 23 kinds of harmful aromatic amine, benzenecontaining chlorine, methylbenzene containing chlorine and phenol containing chlorine on obtained fabric meet limit requirements in an Oeko-Tex Standard100.
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Paragraph 0041-0043; 0044-0046
(2018/04/21)
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- Disperse dye composition and preparation method and use thereof
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A disperse dye composition and a preparation method and use thereof are disclosed, the disperse dye composition comprises a component A, a banned aromatic amine compound, chlorinated phenol, chlorobenzene, chlorotoluene, optional accessories, and other inescapable impurities, the component A comprises one or more compounds of compounds shown as formula (1), the total content of the prohibited aromatic amine compound is 10ppm or below, the total content of various types of the chlorinated phenol is respectively 0.5ppm or below, and the total content of the chlorobenzene and the chlorotoluene is 1ppm or below. All environmentally-friendly indicators of the disperse dye composition meet the requirements of Oeko-Tex Standard 100 (2016). In addition, after a fabric is dyed with the disperse dye composition, and the dyed fabric meets the baby level requirements of the Oeko-Tex Standard 100 (2016).
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Paragraph 0043; 0044; 0045; 0046; 0051; 0052
(2017/07/19)
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- Stable diazonium salts of weakly basic amines—Convenient reagents for synthesis of disperse azo dyes
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A new synthetic strategy for industrially important deep-shade disperse azo dyes was presented in this study. The key procedure is to prepare stable solid diazonium salts of weakly basic amines in the absence of concentrated sulfuric acid. Diazotization by tert-butyl nitrite in ethyl acetate was allowed to proceed in the presence of equivalent 1,5-naphthalenedisulfonic acid as stabilizer of diazonium salts and donor of hydrogen ion for the reaction. The separated solid diazonium salts exhibited good thermal stability. The corresponding disperse azo dyes were subsequently synthesized through the azo-coupling of the prepared solid diazonium salts with a range of aromatic tertiary amines. The azo dyes were produced in short reaction time, excellent yields, mild reaction conditions, simple experimental procedure and low energy consumption.
- Qiu, Jinjing,Tang, Bingtao,Ju, Benzhi,Xu, Yuanji,Zhang, Shufen
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- Clean preparation method for weakly alkaline arylamine azo disperse dye
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The present invention provides a clean preparation method for weakly alkaline arylamine azo disperse dye. The method is characterized in that when a weakly alkaline arylamine diazonium double salt solid is coupled with a coupling component, the coupling component is pretreated to obtain a fine particle dispersion to be coupled with the weakly alkaline arylamine diazonium double salt; and the generated disperse dye is precipitated from the coupling system and is filtered and dried, thereby obtaining the weakly alkaline arylamine azo disperse dye. According to the preparation method provided by the present invention, by using a stable double salt structure of a diazonium salt, during the coupling, the process of adding acid for dissolution can be omitted; the coupling is performed at the normal temperature, and extra cooling is not required; and the method has a broad application prospect.
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Paragraph 0052; 0053; 0054
(2017/01/02)
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