Triphenylphosphine Decomposition of Sulfenyl Thiocarbonates
Several sulfenyl thiocarbonates (RSSCO2CH3) have been decomposed with triphenylphosphine.In the case of R = alkyl, desulfurization takes place to give the S-alkyl thiocarbonate while in the case of R = aryl, a phosphonium salt is likely formed which on chromatographic workup on silica gel is converted to a thiol and triphenylphosphine oxide and sulfide.A mechanistic interpretation is offered.
Harpp, David N.,Granata, Alessandro
p. 271 - 273
(2007/10/02)
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