72050-05-6

Basic information

• Product Name: (p-Chlorobenzyl)sulfenyl methyl thiocarbonate
• CAS NO: 72050-05-6
• Molecular Weight: 248.754
• Mol File: 72050-05-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (p-Chlorobenzyl)sulfenyl methyl thiocarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: (p-Chlorobenzyl)sulfenyl methyl thiocarbonate(72050-05-6)
• EPA Substance Registry System: (p-Chlorobenzyl)sulfenyl methyl thiocarbonate(72050-05-6)

Safety Data

• Hazardous Substances Data: 72050-05-6(Hazardous Substances Data)

Upstream product

• 26555-40-8 metgoxycarbonylsulfenyl chloride 
• 6258-66-8 (4-chlorophenyl)methanethiol 

Downstream Products

• 72050-08-9 S-p-Chlorobenzyl methyl thiocarbonate 

Relevant articles and documents

Triphenylphosphine Decomposition of Sulfenyl Thiocarbonates

Several sulfenyl thiocarbonates (RSSCO2CH3) have been decomposed with triphenylphosphine.In the case of R = alkyl, desulfurization takes place to give the S-alkyl thiocarbonate while in the case of R = aryl, a phosphonium salt is likely formed which on chromatographic workup on silica gel is converted to a thiol and triphenylphosphine oxide and sulfide.A mechanistic interpretation is offered.