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75629-19-5

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Total Synthesis of Mulberry Diels-Alder-Type Adducts Kuwanons G and H
Mulberry Diels-Alder-type adducts (MDAAs) are a group of rare natural polyphenols biosynthetically derived from [4 + 2]-cycloaddition of chalcones and dehydroprenylphenols. In this study, kuwanons G (1) and H (2), two bioactive MDAAs with unique dehydroprenylflavonoid dienes, were totally synthesized for the first time in a biomimetic manner. The key features of the convergent route include the use of the Baker-Venkataraman rearrangement, alkylation of β-diketone, intramolecular cyclization, and Suzuki-Miyaura coupling to achieve the subunit diene.
Luo, Si-Yuan,Tang, Zhuo-Ya,Li, Qingjiang,Weng, Jiang,Yin, Sheng,Tang, Gui-Hua
p. 4786 - 4793
(2021/04/06)

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Chemical Properties

Boiling Point: 942.4°C at 760 mmHg
Flash Point:293.9°C
Density: 1.446g/cm³
Vapor Pressure: 0mmHg at 25°C
PKA: 6.54±0.40(Predicted)
PSA: 209.12000
LogP: 7.33000

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