One pot conversion of alcohols to disulfides mediated by benzyltriethylammonium tetrathiomolybdate
A one pot conversion of alcohols to disulfides in good yields via the activation of a hydroxyl group with DCC or P(NMe2)3 / CCl4 followed by treatment with benzyltriethylammonium tetrathiomolybdate is reported.
Sinha, Surajit,Ilankumaran,Chandrasekaran
p. 14769 - 14776
(2007/10/03)
Sulfur-Sulfur Bond Cleavage Processes. Selective Desulfurization of Trisulfides
The selectivity of sulfur removal in the desulfurization of trisulfides by tertiary phosphorus compounds has been investigated in detail.A mechanistic rationalization is proposed to account for central/terminal sulfur extrusion variation as a function of substrate structure and solvent polarity.
Harpp, David N.,Smith, Roger A.
p. 6045 - 6053
(2007/10/02)
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