Synthesis of ketones via organolithium addition to acid chlorides using continuous flow chemistry
An efficient method for the synthesis of ketones using organolithium and acid chlorides under continuous flow conditions has been developed. In contrast to standard batch chemistry, over-addition of the organolithium to the ketone for the formation of the undesired tertiary alcohol has been minimised representing a direct approach toward ketones.
Moon, Soo-Yeon,Jung, Seo-Hee,Bin Kim,Kim, Won-Suk
p. 79385 - 79390
(2015/10/06)
Sterically stabilized p-quinodimethanes by nucleophilic aromatic substitution
Triarylmethyl cations with a sterically shielded cationic center react with selected C- and N-nucleophiles under nucleophilic aromatic substitution. The resulting dipolar p-quinodimethanes represent highly functionalized extended π systems. Wiley-VCH Verl
Dyker, Gerald,Hagel, Marcel,Muth, Oliver,Schirrmacher, Christian
p. 2134 - 2144
(2007/10/03)
More Articles about upstream products of 859079-13-3