Structure and stereochemistry or toromycin: Studies of its acid-catalyzed rearrangement
An antibiotic from Streptomyces has been shown to be identical with toromycin and gilvocarcin V. Toromycin has been shown by FT NOE difference spectroscopy to be a C-β-fucofuranoside and to undergo acid-catalyzed rearrangement to an approx. 1:1:2.5 mixture of toromycin and the corresponding C-α-fucofuranoside and C-β-fucopyranoside.
Get Best Price for86475-86-7toromycin (1-hydroxy-4(3,4,5-trihydroxy-6-methyl-2H-tetrahydropyran-2-yl)-10,12-dimethoxy-6-oxo-8-vinyl-6H-benzonaphtho<1,2-b>pyran)