THERMAL REARRANGEMENT AND IN VITRO ACTIVITY OF TOROMYCIN AGAINST ANAEROBIC BACTERIA. SIGNIFICANCE OF REARRANGEMENT STUDIES ON THE NATURE OF CHRYSOMYCIN AND THE STRUCTURE OF GILVOCARCIN A.
Structure and stereochemistry or toromycin: Studies of its acid-catalyzed rearrangement
An antibiotic from Streptomyces has been shown to be identical with toromycin and gilvocarcin V. Toromycin has been shown by FT NOE difference spectroscopy to be a C-β-fucofuranoside and to undergo acid-catalyzed rearrangement to an approx. 1:1:2.5 mixture of toromycin and the corresponding C-α-fucofuranoside and C-β-fucopyranoside.
Jain,Simolike,Jackman
p. 599 - 605
(2007/10/02)
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