- N-silylaminotin trichlorides. Synthesis and characterisation by multinuclear magnetic resonance spectroscopy
-
N-Silyl-aminotin trichlorides, R1R2N-SnCl3 [R1 = R2 = SiMe3 (1a), R1 = SiMe3, R2 = 1Bu (1b), R1 = SiMe3, R2 = 9-
- Wrackmeyer, Bernd,Pedall, Andreas,Weidinger, Juergen
-
-
Read Online
- Syntheses, structures, and 1H, 13C{1H} and 119Sn{1H} NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds
-
The synthesis and full characterization, including Nuclear Magnetic Resonance (NMR) data (1H, 13C{1H} and 119Sn{1H}), for a series of Me3SnX (X = O-2,6-tBu2C6H3 (1), (Me3Sn)N(2,6-iPr2C6H3) (3), NH-2,4,6-tBu3C6H2 (4), N(SiMe3)2 (5), NEt2, C5Me5 (6), Cl, Br, I, and SnMe3) compounds in benzene-d6, toluene-d8, dichloromethane-d2, chloroform-d1, acetonitrile-d3, and tetrahydrofuran-d8 are reported. The X-ray crystal structures of Me3Sn(O-2,6-tBu2C6H3) (1), Me3Sn(O-2,6-iPr2C6H3) (2), and (Me3Sn)(NH-2,4,6-tBu3C6H2) (4) are also presented. These compiled data complement existing literature data and ease the characterization of these compounds by routine NMR experiments.
- Lichtscheidl, Alejandro G.,Janicke, Michael T.,Scott, Brian L.,Nelson, Andrew T.,Kiplinger, Jaqueline L.
-
p. 16156 - 16163
(2015/09/15)
-
- -
-
Tin element compounds R3SnE (R = Me or Ph; E = NEt2, OMe or OSnMe3) react with R2N-P=NR (R = SiMe3) (1) by 1,1-addition at phosphorus yielding the P-stannylated iminophosphoranes R3Sn(E)P(N
- Haenssgen, Dieter,Oster, Thomas,Nieger, Martin
-
-