996-37-2

Basic information

• Product Name: NONAMETHYLSTANNASILAZANE
• Synonyms: NONAMETHYLSTANNASILAZANE;1,1,1-trimethyl-N-(trimethylsilyl)-N-(trimethylstannyl)silylamine;1,1,1,3,3,3-Hexamethyl-2-(trimethylstannyl)propanedisilazane;[[bis(trimethylsilyl)amino]-dimethylstannyl]methane;[[bis(trimethylsilyl)amino]-dimethyl-stannyl]methane;bis(trimethylsilyl)-trimethylstannyl-amine
• CAS NO: 996-37-2
• Molecular Formula: C₉H₂₇NSi₂Sn
• Molecular Weight: 324.2
• EINECS: 213-636-0
• Mol File: 996-37-2.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 126°Cat760mmHg
• Flash Point: 30°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 11.9mmHg at 25°C
• CAS DataBase Reference: NONAMETHYLSTANNASILAZANE(CAS DataBase Reference)
• NIST Chemistry Reference: NONAMETHYLSTANNASILAZANE(996-37-2)
• EPA Substance Registry System: NONAMETHYLSTANNASILAZANE(996-37-2)

Safety Data

• Hazardous Substances Data: 996-37-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H18NSi2.3CH3.Sn/c1-8(2,3)7-9(4,5)6;;;;/h1-6H3;3*1H3;/q-1;;;;+1/rC6H18NSi2.C3H9Sn/c1-8(2,3)7-9(4,5)6;1-4(2)3/h1-6H3;1-3H3/q-1;+1

Upstream product

• 1066-45-1 trimethyltin(IV)chloride 
• 4039-32-1 lithium hexamethyldisilazane 
• 186540-64-7 diethylamino-bis(trimethylsilyl)amino-trimethylsilylimino-trimethylstannyl-phosphorane 
• 40949-94-8 potassium hexamethylsilazane 

Downstream Products

• 503027-47-2 N,N'-bis(trimethylsilyl)sulfurdiimide 
• 18810-65-6 1,3-bis-(pentafluorophenyl)-2-thia-1,3-diazaallene 
• 18156-13-3 hexamethylsilastannoxane 
• 123394-96-7 1-pentafluorophenyl-3-trimethylsilyl-1,3-diaza-2-thiaallene 
• 117847-51-5 1,3-bis-(p-fluorophenyl)-2-thia-1,3-diazaallene 
• 123394-94-5 1,3-bis(2,6-difluorophenyl)-1,3-diaza-2-thiaallene 
• 123394-95-6 1-(2,3,5,6-tetrafluorophenyl)-2-thia-1,3-diaza-4-(trimethylsilyl)-allene 
• 75207-80-6 1,3-bis(2,3,5,6-tetrafluorophenyl)-1,3-diaza-2-thiaallene 
• 123428-02-4 1-(2,3,5,6-tetrafluoro-p-tolyl)-3-trimethylsilyl-1,3-diaza-2-thiaallene 
• 75207-81-7 1,3-bis(2,3,5,6-tetrafluoro-p-tolyl)-1,3-diaza-2-thiaallene 
• 123394-97-8 1-(4-Trifluoromethyl-tetrafluorophenyl)-3-trimethylsilyl-1,3-diaza-2-thiaallene 
• 942623-33-8 [Sn(CH₃)3(HN(CH₃)2)2]⁽¹⁺⁾*B(C₆F₅)4^(1-)=[Sn(CH₃)3(HN(CH₃)2)2]B(C₆F₅)4 
• 123394-93-4 1-(2,6-dimethylphenyl)-3-trimethylstannyl-1,3-diaza-2-thiaallene 
• 15148-19-3 1,3-bis(p-nitrophenyl)-2-thia-1,3-diazaallene 

Relevant articles and documents

N-silylaminotin trichlorides. Synthesis and characterisation by multinuclear magnetic resonance spectroscopy

N-Silyl-aminotin trichlorides, R1R2N-SnCl3 [R1 = R2 = SiMe3 (1a), R1 = SiMe3, R2 = 1Bu (1b), R1 = SiMe3, R2 = 9-

Syntheses, structures, and 1H, 13C{1H} and 119Sn{1H} NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds

The synthesis and full characterization, including Nuclear Magnetic Resonance (NMR) data (1H, 13C{1H} and 119Sn{1H}), for a series of Me3SnX (X = O-2,6-tBu2C6H3 (1), (Me3Sn)N(2,6-iPr2C6H3) (3), NH-2,4,6-tBu3C6H2 (4), N(SiMe3)2 (5), NEt2, C5Me5 (6), Cl, Br, I, and SnMe3) compounds in benzene-d6, toluene-d8, dichloromethane-d2, chloroform-d1, acetonitrile-d3, and tetrahydrofuran-d8 are reported. The X-ray crystal structures of Me3Sn(O-2,6-tBu2C6H3) (1), Me3Sn(O-2,6-iPr2C6H3) (2), and (Me3Sn)(NH-2,4,6-tBu3C6H2) (4) are also presented. These compiled data complement existing literature data and ease the characterization of these compounds by routine NMR experiments.