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DICHLORODIETHYLSILANE

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Name

DICHLORODIETHYLSILANE

EINECS 217-005-0
CAS No. 1719-53-5 Density 1.026 g/cm3
PSA 0.00000 LogP 2.94600
Solubility insoluble in water Melting Point -96 °C
Formula C4H10Cl2Si Boiling Point 127.798 °C at 760 mmHg
Molecular Weight 157.115 Flash Point 28.333 °C
Transport Information UN 1767 8/PG 2 Appearance colourless liquid
Safety 26-36/37/39-45-25-16-43 Risk Codes 11-14-34-37-10
Molecular Structure Molecular Structure of 1719-53-5 (Dichlorodiethylsilane) Hazard Symbols FlammableF,CorrosiveC
Synonyms

Dichlorodiethylsilane;Diethyldichlorosilane;Diethyldichlorosilicon;

Article Data 67

DICHLORODIETHYLSILANE Synthetic route

115-21-9

ethyltrichlorosilane

78-07-9

ethyltriethoxy silane

75-00-3

chloroethane

A

597-67-1

ethoxytriethylsilane

B

5021-93-2

diethyldiethoxysilane

C

1719-53-5

diethyldichlorosilane

Conditions
ConditionsYield
With magnesium at 60℃; for 1h;A 18.5%
B 74.2%
C 5.2%
75-00-3

chloroethane

A

115-21-9

ethyltrichlorosilane

B

1719-53-5

diethyldichlorosilane

Conditions
ConditionsYield
With copper; silicon In neat (no solvent) C2H5Cl and Si-Cu (8:2; heating of the pressed mixt. at 900-930°C in vac. for 2 h) at about 275°C;;A 17%
B 71%
With Si-Cu In neat (no solvent) C2H5Cl and Si-Cu (8:2; heating of the pressed mixt. at 900-930°C in vac. for 2 h) at about 275°C;;A 17%
B 71%
With copper; silicon at 300 - 325℃;
With copper; silicon at 300 - 325℃;
1789-58-8

ethyldichlorosilane

74-86-2

acetylene

A

10138-21-3

(dichloro)(ethyl)vinylsilane

B

1,2-bis(dichloroethylsilyl)ethane

C

1719-53-5

diethyldichlorosilane

Conditions
ConditionsYield
With bis(tributylphosphine)dichloropalladium(II) In xylene at 80℃; for 3h;A 23%
B 70%
C 5%
With bis-triphenylphosphine-palladium(II) chloride In xylene at 80℃; for 3h; Product distribution; other silanes, var. paladdium complexes and reaction time;A 62%
B 23%
C 12%
With bis-triphenylphosphine-palladium(II) chloride In xylene at 80℃; for 3h;A 62%
B 23%
C 12%
With palladium(II) acetylacetonate In xylene at 80℃; for 3h;A 6%
B 7%
C 25%
115-21-9

ethyltrichlorosilane

78-10-4

tetraethoxy orthosilicate

75-00-3

chloroethane

A

78-07-9

ethyltriethoxy silane

B

597-67-1

ethoxytriethylsilane

C

5021-93-2

diethyldiethoxysilane

D

1719-53-5

diethyldichlorosilane

Conditions
ConditionsYield
With magnesium at 50 - 100℃;A 5.7%
B 17.9%
C 63.3%
D 9.4%
With magnesium at 60℃; for 1h; Temperature;A 15.1%
B 21.7%
C 46.3%
D 14.1%
115-21-9

ethyltrichlorosilane

78-10-4

tetraethoxy orthosilicate

75-00-3

chloroethane

A

597-67-1

ethoxytriethylsilane

B

5021-93-2

diethyldiethoxysilane

C

1719-53-5

diethyldichlorosilane

Conditions
ConditionsYield
With magnesium at 50 - 100℃;A 18.4%
B 49.8%
C 15.6%
With magnesium at 60℃; for 1h; Temperature;A 27.3%
B 33.7%
C 24.7%
925-90-6

ethylmagnesium bromide

1719-53-5

diethyldichlorosilane

Conditions
ConditionsYield
With tetrachlorosilane45%
With tetrachlorosilane
With tetrachlorosilane; diethyl ether
115-21-9

ethyltrichlorosilane

78-07-9

ethyltriethoxy silane

75-00-3

chloroethane

A

994-30-9

triethylsilyl chloride

B

597-67-1

ethoxytriethylsilane

C

5021-93-2

diethyldiethoxysilane

D

1719-53-5

diethyldichlorosilane

Conditions
ConditionsYield
With magnesium at 60℃; for 1h;A 5.2%
B 18%
C 43.4%
D 29.7%
75-00-3

chloroethane

A

1789-58-8

ethyldichlorosilane

B

1719-53-5

diethyldichlorosilane

Conditions
ConditionsYield
With Si-Cu-Co In neat (no solvent) byproducts: (CH3)3SiCl, HSiCl3, SiCl4; C2H5Cl and Si-Cu-Co (88:10:2) activated with CuCl-CuCl2 at 340-360°C;;A 30%
B 40%
With Si-Cu-Co In neat (no solvent) byproducts: (CH3)3SiCl, HSiCl3, SiCl4; C2H5Cl and Si-Cu-Co (88:10:2) activated with CuCl-CuCl2 at 340-360°C;;A 30%
B 40%
115-21-9

ethyltrichlorosilane

78-10-4

tetraethoxy orthosilicate

75-00-3

chloroethane

A

994-30-9

triethylsilyl chloride

B

597-67-1

ethoxytriethylsilane

C

5021-93-2

diethyldiethoxysilane

D

1719-53-5

diethyldichlorosilane

Conditions
ConditionsYield
With magnesium at 50 - 100℃;A 8.5%
B 20.7%
C 39.4%
D 28.8%
75-00-3

chloroethane

A

115-21-9

ethyltrichlorosilane

B

10026-04-7, 53609-55-5

tetrachlorosilane

C

994-30-9

triethylsilyl chloride

D

1719-53-5

diethyldichlorosilane

Conditions
ConditionsYield
With Si-Cu In neat (no solvent) Si-Cu (9:1) and C2H5Cl at 300-325°C;;A 27%
B 37%
C n/a
D 26%
With Si-Cu In neat (no solvent) Si-Cu (9:1) and C2H5Cl at 300-325°C;;A 27%
B 37%
C n/a
D 26%

DICHLORODIETHYLSILANE Chemical Properties

Product Name: Dichlorodiethylsilane (CAS NO.1719-53-5)


Molecular Formula: C4H10Cl2Si
Molecular Weight: 157.11g/mol
Mol File: 1719-53-5.mol
Einecs: 217-005-0
Appearance: A colorless liquid with a pungent odor
Melting Point: -96 °C
Boiling point: 127.8 °C at 760 mmHg
Storage Temperature: Flammables area
Flash Point: 28.3 °C
Density: 1.05 g/mL at 25 °C(lit.)
Refractive index: n20/D 1.43(lit.)
Water Solubility: Insoluble
Sensitive: Moisture Sensitive
Stability: Stable. Incompatible with strong oxidizing agents. May decompose upon exposure to water or moisture.
Surface Tension: 20.9 dyne/cm
Enthalpy of Vaporization: 35.04 kJ/mol
Vapour Pressure: 13.3 mmHg at 25°C 
Product Categories: Analytical Chemistry; Dichlorosilanes; Dichlorosilanes (for Polysilanes); Functional Materials; GC Derivatizing Reagents; Pentafluorophenylsilylation, etc. (GC Derivatizing Reagents); Reagent for High-Performance Polymer Research; Si (Classes of Silicon Compounds); Si-Cl Compounds; Silylation (GC Derivatizing Reagents); Protecting and Derivatizing Reagents; Protection and Derivatization; Silicon-Based

DICHLORODIETHYLSILANE Toxicity Data With Reference

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LDLo intraperitoneal 100mg/kg (100mg/kg)   Journal of Industrial Hygiene and Toxicology. Vol. 30, Pg. 332, 1948.
rat LDLo oral 1gm/kg (1000mg/kg)   Journal of Industrial Hygiene and Toxicology. Vol. 30, Pg. 332, 1948.

DICHLORODIETHYLSILANE Consensus Reports

Reported in EPA TSCA Inventory.

DICHLORODIETHYLSILANE Safety Profile

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
Safety Information of Dichlorodiethylsilane (CAS NO.1719-53-5):
Hazard Codes: F,C
Risk Statements: 11-14-34-37-10 
10:  Flammable
11:  Highly Flammable
14:  Reacts violently with water
34:  Causes burns
37:  Irritating to the respiratory system
Safety Statements: 26-36/37/39-45-25-16-43
16:  Keep away from sources of ignition - No smoking
25:  Avoid contact with eyes 
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36:  Wear suitable protective clothing  
37:  Wear suitable gloves  
39:  Wear eye/face protection
43:  In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water) 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)

DICHLORODIETHYLSILANE Standards and Recommendations

DOT Classification:  8; Label: Corrosive, Flammable Liquid

DICHLORODIETHYLSILANE Specification

 Dichlorodiethylsilane ,its CAS NO. is 1719-53-5,the synonyms is Diethylsiliciumdichlorid ; Diethyldichlorosilane ; Dichlorodiethyl-silan ; Diethyldichlorosilicon ; Silane, dichlorodiethyl- ; Silane,dichlorodiethyl- ; Diethyldichlorosilane(dichlorodiethylsilane) .

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