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Dibenzo(def,p)chrysene

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Name

Dibenzo(def,p)chrysene

EINECS N/A
CAS No. 191-30-0 Density 1.28g/cm3
PSA 0.00000 LogP 6.89040
Solubility N/A Melting Point 228.05°C
Formula C24H14 Boiling Point 630.6°C at 760 mmHg
Molecular Weight 302.375 Flash Point 349.8°C
Transport Information N/A Appearance N/A
Safety Confirmed carcinogen with experimental tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes. Risk Codes 40
Molecular Structure Molecular Structure of 191-30-0 (DIBENZO(A,I)PYRENE) Hazard Symbols
Synonyms

1,2,9,10-Dibenzopyrene;1,2:3,4-Dibenzopyrene; 2,3:4,5-Dibenzpyrene; 4,5,6,7-Dibenzpyrene; Ba51-090462; Dibenzo[a,l]pyrene; NSC 90324

Article Data 12

Dibenzo(def,p)chrysene Synthetic route

N-[2-(5,6-dihydro-4H-benz[de]anthracen-7-yl)benzylidene]aniline

191-30-0

Dibenzo[a,l]pyrene

Conditions
ConditionsYield
Stage #1: N-[2-(5,6-dihydro-4H-benz[de]anthracen-7-yl)benzylidene]aniline With potassium hydroxide In N,N-dimethyl-formamide at 100℃; for 1h;
Stage #2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In benzene for 0.5h; Heating;
88%
1013933-57-7

9-(2-methoxy-vinyl)-benzo[g]chrysene

191-30-0

Dibenzo[a,l]pyrene

Conditions
ConditionsYield
With methanesulfonic acid In dichloromethane at 20℃; for 2.5h;75%
13322-54-8

Pentahelicen-3-carbonsaeure-methylester

191-30-0

Dibenzo[a,l]pyrene

Conditions
ConditionsYield
ueber Dibenzo<def,p>chrysen-8-ol;
56-55-3

benz[a]anthracene

71-43-2

benzene

191-30-0

Dibenzo[a,l]pyrene

Conditions
ConditionsYield
With aluminium trichloride; ortho-toluoyl chloride
10383-87-6

1-Phenylbenzanthracen

191-30-0

Dibenzo[a,l]pyrene

Conditions
ConditionsYield
With aluminium trichloride; tin(IV) chloride
17181-10-1

C24H14O

191-30-0

Dibenzo[a,l]pyrene

Conditions
ConditionsYield
With sodium chloride; zinc(II) chloride; zinc
7424-73-9

12-phenyl-benz[a]anthracene

191-30-0

Dibenzo[a,l]pyrene

Conditions
ConditionsYield
With aluminium trichloride
4389-09-7

1,10-trimethylenephenanthrene

191-30-0

Dibenzo[a,l]pyrene

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: 86 percent / Br2 / CCl4 / 2 h / Heating
2.1: 61 percent / CsF / Pd(PPh3)4 / dimethylformamide / 24 h
3.1: 96 percent / molecular sieves 4 Angstroem / CH2Cl2 / 4 h
4.1: KOH / dimethylformamide / 1 h / 100 °C
4.2: 88 percent / DDQ / benzene / 0.5 h / Heating
View Scheme
681215-15-6

7-bromo-5,6-dihydro-4H-benz[de]anthracene

191-30-0

Dibenzo[a,l]pyrene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: 61 percent / CsF / Pd(PPh3)4 / dimethylformamide / 24 h
2.1: 96 percent / molecular sieves 4 Angstroem / CH2Cl2 / 4 h
3.1: KOH / dimethylformamide / 1 h / 100 °C
3.2: 88 percent / DDQ / benzene / 0.5 h / Heating
View Scheme
681215-16-7

7-(2-formylphenyl)-5,6-dihydro-4H-benz[de]anthracene

191-30-0

Dibenzo[a,l]pyrene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 96 percent / molecular sieves 4 Angstroem / CH2Cl2 / 4 h
2.1: KOH / dimethylformamide / 1 h / 100 °C
2.2: 88 percent / DDQ / benzene / 0.5 h / Heating
View Scheme

Dibenzo(def,p)chrysene Chemical Properties

Chemical Name: Dibenzo(a,i)pyrene
CAS No.: 191-30-0
EINECS: 205-886-4
Molecular Formula: C24H14
Molecular Weight: 302.37 g/mol
Density: 1.313 g/cm3 
Flash Point: 282 °C
Boiling Point: 552.3 °C at 760 mmHg 
Storage temp.: 2-8°C
Following is the structure of Dibenzo(def,p)chrysene (191-30-0):


Product Categories about Dibenzo(def,p)chrysene (191-30-0) are Alpha Sort ; D ; DAlphabetic ; DIA - DIC ; Volatiles/ Semivolatiles
The chemical synonymous of Dibenzo(def,p)chrysene (191-30-0) are Dibenzo(A,I)Pyrene ; Dibenz(A,L)Pyrene ; 3,4,9,10-Dibenzopyrene ; 1,2,3,4-Dibenzpyrene ; 1,2,9,10-Dibenzopyrene

Dibenzo(def,p)chrysene Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 32 (1983),p. 343.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Limited Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 3 (1973),p. 224.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) .

Dibenzo(def,p)chrysene Safety Profile

Confirmed carcinogen with experimental tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes:
Xn: Harmful
Risk Statements about Dibenzo(def,p)chrysene (191-30-0):
R40 Limited evidence of a carcinogenic effect.
Safety Statements about Dibenzo(def,p)chrysene (191-30-0):
S23 Do not breathe vapour.
S24/25: Avoid contact with skin and eyes.
S36/37: Wear suitable protective clothing and gloves.

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