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Diphenyliodonium hexafluorophosphate

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Name

Diphenyliodonium hexafluorophosphate

EINECS 261-134-5
CAS No. 58109-40-3 Density N/A
PSA 13.59000 LogP 3.19740
Solubility N/A Melting Point 140-144 °C(lit.)
Formula C12H10I.F6P Boiling Point N/A
Molecular Weight 426.08 Flash Point N/A
Transport Information N/A Appearance N/A
Safety 26-36/37/39-45 Risk Codes 34
Molecular Structure Molecular Structure of 58109-40-3 (Diphenyliodonium hexafluorophosphate) Hazard Symbols CorrosiveC
Synonyms

Iodonium, diphenyl-, hexafluorophosphate(1-);Iodonium Diphenyl Hexafluorophosphate;

Article Data 5

Diphenyliodonium hexafluorophosphate Synthetic route

591-50-4

iodobenzene

71-43-2

benzene

58109-40-3

diphenyliodonium hexafluorophosphate

Conditions
ConditionsYield
With hexafluorophosphoric acid; 3-chloro-benzenecarboperoxoic acid

diphenyliodonium 4-nitrophenolate

A

1124-31-8

potassium 4-nitrophenolate

B

58109-40-3

diphenyliodonium hexafluorophosphate

Conditions
ConditionsYield
With potassium hexafluorophosphate In acetonitrile at 20℃; Equilibrium constant; Temperature; Inert atmosphere;

diphenyliodonium 4-nitrophenolate

3109-63-5

tert-butylammonium hexafluorophosphate(V)

A

3002-48-0

tetra-n-butylammonium p-nitrophenoxide

B

58109-40-3

diphenyliodonium hexafluorophosphate

Conditions
ConditionsYield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;
16212-05-8

(allylsulfonyl)benzene

58109-40-3

diphenyliodonium hexafluorophosphate

16212-07-0

trans-cinnamyl phenyl sulfone

Conditions
ConditionsYield
With palladium diacetate; sodium hydrogencarbonate In acetonitrile at 50℃; for 22h;99%
120-72-9

indole

58109-40-3

diphenyliodonium hexafluorophosphate

948-65-2

2-phenyl-indole

Conditions
ConditionsYield
Stage #1: indole With C64H56N6P2Pd2 In acetic acid at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: diphenyliodonium hexafluorophosphate In acetic acid at 24.84℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
99%
Stage #1: indole With Pd2[(C6H4)PPh2]2[O2CC6H5]2; acetic acid at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: diphenyliodonium hexafluorophosphate at 24.84℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
99%
1003-68-5

5-methyl-2-pyridone

58109-40-3

diphenyliodonium hexafluorophosphate

53179-13-8

Pirfenidone

Conditions
ConditionsYield
With triethylamine; copper(l) chloride In toluene at 20℃; for 0.5h; Inert atmosphere;99%
139-66-2

diphenyl sulfide

58109-40-3

diphenyliodonium hexafluorophosphate

57835-99-1

triphenylsulphonium hexafluorophosphate

Conditions
ConditionsYield
With copper(II) benzoate In chlorobenzene at 125℃; under 2068.65 Torr; for 0.0333333h; Inert atmosphere; Microwave irradiation;98%
18085-02-4

1,2-diacetoxy-3-butene

58109-40-3

diphenyliodonium hexafluorophosphate

119420-99-4

(E)-4-phenylbut-3-ene-1,2-diyl diacetate

Conditions
ConditionsYield
With palladium diacetate; sodium hydrogencarbonate In acetonitrile at 50℃; for 20h;98%
603-76-9

1-methylindole

58109-40-3

diphenyliodonium hexafluorophosphate

3558-24-5

1-methyl-2-phenyl-1H-indole

Conditions
ConditionsYield
With Pd2[(C6H4)PPh2]2[CF3C(O)CHC(O)CF3]2 In acetic acid at 24.84℃; for 30h; Catalytic behavior; Reagent/catalyst; Time; Solvent; Inert atmosphere; Schlenk technique;98%
Stage #1: 1-methylindole With Pd2[(C6H4)PPh2]2[O2CC6H5]2; acetic acid at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: diphenyliodonium hexafluorophosphate at 24.84℃; for 10h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
97%
1195763-38-2

2-(phenylthio)thioxanthone

123215-04-3

potassium trifluorotris(pentafluoroethyl)phosphate

58109-40-3

diphenyliodonium hexafluorophosphate

diphenyl-2-thioxanthonylsulfonium tris(pentafluoroethyl)trifluorophosphate

Conditions
ConditionsYield
Stage #1: 2-(phenylthio)thioxanthone; diphenyliodonium hexafluorophosphate With copper(II) benzoate In chlorobenzene at 120 - 125℃; for 3h;
Stage #2: potassium tris(pentafluoroethyl)trifluorophosphate In dichloromethane; water at 25℃; for 2h;
98%
Stage #1: 2-(phenylthio)thioxanthone; diphenyliodonium hexafluorophosphate With copper(II) benzoate In chlorobenzene at 120 - 125℃; for 3h;
Stage #2: potassium tris(pentafluoroethyl)trifluorophosphate In dichloromethane; water at 25℃; for 2h;
Stage #1: 2-(phenylthio)thioxanthone; diphenyliodonium hexafluorophosphate With copper(II) benzoate In chlorobenzene at 120 - 125℃; for 3h;
Stage #2: potassium tris(pentafluoroethyl)trifluorophosphate In dichloromethane; water at 25℃; for 2h;

Diphenyliodonium hexafluorophosphate Specification

The Diphenyliodonium hexafluorophosphate with the CAS number 58109-40-3 is also called Iodonium Diphenyl Hexafluorophosphate. Its molecular formula is C12H10I.F6P. The EINECS registry number is 261-134-5. This chemical belongs to the following product categories: (1)Diphenyliodonium Compounds; (2)Functional Materials; (3)Hypervalent Iodine Compounds; (4)Iodonium Sulfonium & Oxonium Compounds; (5)Photopolymerization Initiators; (6)Synthetic Organic Chemistry; (7)Hypervalent Iodine; (8)Oxidation; (9)Synthetic Reagents; (10)Cationic PhotoinitiatorsMicro/Nanoelectronics; (11)FluoridesSelf Assembly&Contact Printing; (12)Electronic Chemicals; (13)Organic Photoinitiators; (14)Photoacid Generators (PAGs); (15)Photoresists; (16)Polymerization Initiators.

Properties Computed from Structure: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 7; (3)Rotatable Bond Count: 2; (4)Exact Mass: 425.946899; (5)MonoIsotopic Mass: 425.946899; (6)Topological Polar Surface Area: 0; (7)Heavy Atom Count: 20; (8)Formal Charge: 0; (9)Complexity: 179; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 2.

While using this chemical, you should be very cautious. This chemical can cause burns. Therefore, you should take the following instructions. Firstly, you should wear suitable protective clothing, gloves and eye/face protection. Then in case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Finally in case of accident or if you feel unwell, you should seek medical advice immediately (show the label whenever possible).

You can still convert the following datas into molecular structure:
(1)SMILES: F[P-](F)(F)(F)(F)F.[I+](c1ccccc1)c2ccccc2
(2)InChI: InChI=1/C12H10I.F6P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-7(2,3,4,5)6/h1-10H;/q+1;-1
(3)InChIKey: DSSRLRJACJENEU-UHFFFAOYAG

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