Bulletin of the Chemical Society of Japan p. 3205 - 3210 (1988)
Update date:2022-08-02
Topics:
Tsuboi, Sadao
Kohara, Noriyuki
Doi, Katsumi
Utaka, Masanori
Takeda, Akira
Treatment of α-(dimethythiocarbamoylthio) ketones with bakers' yeast afforded the corresponding chiral alcohols in high yields with high enentiomeric excess (in most cases, more than 96 percent ee). α- (Dimethylthiocarbamoylthio) aldehydes were reduced to give chiral α-(dimethylthiocarbamoylthio) alcohols in 69-92 percent yields with 32-63 percent ee, which were converted to chiral 1,2-epitio derivatives.
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(1988)Doi:10.1021/np900534v
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(1988)