Tetrahedron Letters p. 3541 - 3544 (1990)
Update date:2022-07-29
Topics: Stereoselective Free-Radical Cyclization Sugar Template Sulfonyl Radical Synthetic Tool Functionalized Glycosides
Nouguier, Robert
Lesueur, Catherine
Riggi, Enzo de
Bertrand, Michele Paula
Virgili, Albert
The addition of a sulphonyl radical to the external double bond of an allyl glycal generates a pro-chiral carbon radical which adds to the glycal double bond with a high diastereoselectivity.Through three consecutive radical steps, the configurations of three new asymmetric centers are controlled.
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