Tetrahedron Asymmetry p. 4007 - 4010 (1997)
Update date:2022-09-26
Topics:
Harwood, Laurence M.
Tyler, Simon N. G.
Anslow, A. Susan
MacGilp, Iain D.
Drew, Michael G. B.
(5S)-5-Phenyl-5,6-dihydro-2H-1,4-oxazin-2-one 2 undergoes Lewis acid-mediated chemo- and diastereoselective nucleophilic addition of Grignard reagents to furnish adducts 3 which can be dismantled to allow ready access to enantiomerically pure (S)-α-amino acids 4.
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