Organic Letters
Letter
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or transition-metal catalysts are avoided. The controlled
experiments indicate involvement of radical mechanism and
intramolecular nature of the rearrangement under this protocol.
Application of the developed protocol and Pd-catalyzed double
C−H activation as important steps have been demonstrated in
the formal total synthesis of the antimalarial natural product
isocryptolepine.
̀
292. (i) Jonckers, T. H. M.; Maes, B. U. W.; Lemiere, G. L. F.;
ASSOCIATED CONTENT
* Supporting Information
The Supporting Information is available free of charge on the
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Experimental procedures, spectral and analytical data, and
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AUTHOR INFORMATION
Corresponding Author
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Notes
The authors declare no competing financial interest.
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ACKNOWLEDGMENTS
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P.S.M. thanks CSIR-New Delhi for the research fellowship.
S.B.M. gratefully acknowledges generous financial support from
DST, CSIR-ORIGIN, CSIR-OSDD New Delhi, and CSIR-NCL
(start-up grant).
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