Chemical Science
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the formation of ruthenium hydride species from isopropanol.
Mechanistic studies revealed that the effect of MgO can be (1)
acceleration of the imine hydrogenation step by the electronic
tuning of Ru particles, and (2) the anchoring effect that provides
large dispersion and small particle size. These results with the
metal hydride species are expected to provide a design guide for
new heterogeneous catalysts for hydrogen-involving reactions.
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Conflicts of interest
There are no conicts to declare.
Acknowledgements
This work was nancially supported by the Advanced Low
Carbon Technology Research and Development Program
(ALCA) of the Japan Science and Technology Agency (JST)
(JPMJAL1205) and a fund from the Grants-in-Aid for Japan
Society for the Promotion of Science (JSPS) Fellows and for
Scientic Research from the Ministry of Education, Culture,
Science, Sports, and Technology (MEXT) of Japan (18H05251).
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