Journal of Organometallic Chemistry p. 47 - 52 (1986)
Update date:2022-08-17
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Matsuda, Isamu
Sato, Susumu
Regiodefined α-monobromo ketones are readily obtained by the interaction of bromine with an equivalent of α-trimethylsilyl ketones, in an excellent yield.Analogoes selective substitution of the trimethylsilyl group on phenylthio and phenylseleno groups can be attained by the reaction of phenylsulfenyl chloride or phenylselenenyl bromide with α-trimethylsilyl ketones in the presence of zinc bromide in dichloromethane.
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