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ACS Catalysis
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been investigated as catalyst in the reduction of CO2 into
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methanol by BH3.SMe2. The use of a coordinating solvent
like THF was required for the catalysis to occur. TON of up
to 2800 can be obtained with a catalyst loading as low as
0.1 mol%.
ASSOCIATED CONTENT
Supporting Information
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Details of experimental procedures, physical properties of
new compounds, tables of crystal data, atomic positions,
and displacement parameters, anisotropic displacement
parameters, and bond lengths and bond angles in CIF forꢀ
mat. The Supporting Information is available free of charge
on the ACS Publications website.
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AUTHOR INFORMATION
Corresponding Author
* Eꢀmail: mezailles@chimie.upsꢀtlse.fr
Notes
The authors declare no competing financial interests.
ACKNOWLEDGMENTS
Financial support from CNRS and Université de Toulouse is
acknowledged. M.L. and A.P. thank MESR and ANRꢀ14ꢀ
CE06ꢀ0006 for their Ph.D. funding respectively. N.M. thanks
the “Région MidiꢀPyrénées” for generous funding. The auꢀ
thors are grateful to CalMip (CNRS, Toulouse, France) for
calculation facilities.
This article is dedicated to the memory of Prof. P. Le Floch.
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Ber. 1987, 120, 659ꢀ667. (b) Boese, R.; Paetzold, P.; Tapper, A.;
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